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Dynamic combinatorial libraries: new opportunities in systems chemistry
Open accessAbstract
Combinatorial chemistry is a tool for selecting molecules with special properties. Dynamic combinatorial chemistry started off aiming to be just that. However, unlike ordinary combinatorial chemistry, the interconnectedness of dynamic libraries gives them an extra dimension. An understanding of these molecular networks at systems level is essential for their use as a selection tool and creates exciting new opportunities in systems chemistry. In this feature article we discuss selected examples and considerations related to the advanced exploitation of dynamic combinatorial libraries for their originally conceived purpose of identifying strong binding interactions. Also reviewed are examples illustrating a trend towards increasing complexity in terms of network behaviour and reversible chemistry. Finally, new applications of dynamic combinatorial chemistry in self-assembly, transport and self-replication are discussed.
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Cites
Welcome home, systems chemists
von Kiedrowski, G., Otto, S., & Herdewijn, P. (2010) · Journal of Systems Chemistry · doi:10.1186/1759-2208-1-1 · Cited by 102
Self-citation
Cited by
Prebiotic Systems Chemistry: New Perspectives for the Origins of Life
Ruiz-Mirazo, K., Briones, C., & de la Escosura, A. (2014) · Chemical Reviews · doi:10.1021/cr2004844 · Cited by 930
Herrmann, A. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60336a · Cited by 351
Evolution of Dynamic Combinatorial Chemistry
Cougnon, F. B. L., & Sanders, J. K. M. (2012) · Accounts of Chemical Research · doi:10.1021/ar200240m · Cited by 316
Metadata
- Authors
- Hunt, R. A. R., & Otto, S.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 47
- Issue
- 3
- Pages
- 847-858
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2162483151
- Cited by
- 198
- References
- 1
- FWCI
- 11.37
- Type
- journal article
- Language
- en
- Open access
- green
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