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Photocatalytic hydrogen evolution on dye-sensitized mesoporous carbon nitride photocatalyst with magnesium phthalocyanine

Takanabe, Kazuhiro, Kamata, Kumiko, Wang, Xinchen, Antonietti, Markus, Kubota, Jun, Domen, Kazunari·2010·Physical Chemistry Chemical Physics

Abstract

Spectral sensitization of a mesoporous graphite carbon nitride (mpg-C(3)N(4)) photocatalyst was investigated by depositing magnesium phthalocyanine (MgPc) to expand the absorption to wavelengths longer than those of the principal mpg-C(3)N(4). The obtained sample, MgPc/Pt/mpg-C(3)N(4) (Pt as a cocatalyst) showed stable photocatalytic evolution of hydrogen from aqueous solution in the presence of sacrificial reagents (triethanolamine), even under irradiation at wavelengths longer than 600 nm. Increasing the amount of MgPc led to ordered MgPc aggregation on the photocatalyst surfaces. The rate of photocatalytic hydrogen evolution was highest on a sample with an amount of MgPc corresponding to a monolayer on the Pt/mpg-C(3)N(4) photocatalyst surface. The obtained action spectra of hydrogen evolution and the observation that the amount of evolved hydrogen substantially surpassed the amount of MgPc, confirm that the introduced MgPc functioned as a photocatalytic sensitizer.

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Metadata

Authors
Takanabe, K., Kamata, K., Wang, X., Antonietti, M., Kubota, J., & Domen, K.
Venue
Physical Chemistry Chemical Physics
Published
2010
Volume
12
Issue
40
Pages
13020
ISSN
  • 1463-9076 (ISSN-L)
  • 1463-9084
OpenAlex
W2083836166
Cited by
360
References
1
FWCI
6.97
Type
journal article
Language
en
Open access
closed

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Takanabe, K., Kamata, K., Wang, X., Antonietti, M., Kubota, J., & Domen, K. (2010). Photocatalytic hydrogen evolution on dye-sensitized mesoporous carbon nitride photocatalyst with magnesium phthalocyanine. Physical Chemistry Chemical Physics. https://doi.org/10.1039/c0cp00611d

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