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Cluster-based inorganic–organic hybrid materials
Abstract
Clusters as building blocks have been used for two types of inorganic-organic hybrid materials. The first are hybrid polymers, with polymer-like properties and structures, where the cluster units crosslink the polymer chains. They are prepared by co-polymerization of organic monomers with functional ligands attached to the clusters. The second type is crystalline metal-organic framework structures which are obtained by coordination chemistry approaches, i.e. by coordinating multifunctional organic ligands to cluster units. This tutorial review shows that both types of cluster-based materials are limiting cases with many options for varying both the cluster units as well as the connecting organic entities.
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Cited by
Gas Sensors Based on Chemi-Resistive Hybrid Functional Nanomaterials
Jian, Y., Hu, W., Zhao, Z., Cheng, P., Haick, H., Yao, M., & Wu, W. (2020) · Nano-Micro Letters · doi:10.1007/s40820-020-0407-5 · Cited by 429
Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters
Fang, W.-H., Zhang, L., & Zhang, J. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00511c · Cited by 348
Li, L., Chakrabarty, S., Spyrou, K., Ober, C. K., & Giannelis, E. P. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01506 · Cited by 126
Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals
Van den Eynden, D., Pokratath, R., & De Roo, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c01008 · Cited by 83
Mixed-ligand zinc-oxoclusters: Efficient chemistry for high resolution nanolithography
Thakur, N., Bliem, R., Mochi, I., Vockenhuber, M., Ekinci, Y., & Castellanos, S. (2020) · Journal of Materials Chemistry C · doi:10.1039/d0tc03597a · Cited by 52
Metadata
- Authors
- Schubert, U.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 40
- Issue
- 2
- Pages
- 575-582
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2121242870
- Cited by
- 303
- References
- 0
- FWCI
- 0.48
- Type
- journal article
- Language
- en
- Open access
- closed
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