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The first porous MOF with photoswitchable linker molecules
Open accessAbstract
We synthesized a porous twofold interpenetrated MOF [Zn(2)(NDC)(2)(1)] (coined CAU-5) using 3-azo-phenyl-4,4'-bipyridine (1), 2,6-naphthalenedicarboxylic acid, and Zn(NO(3))(2)·6H(2)O. The azo-functionality protrudes into the pores, and can be switched, by irradiation with UV light (365 nm), from the thermodynamically stable trans-isomer to the cis-isomer. Back-switching was achieved thermally and with an irradiation wavelength of λ(max) = 440 nm.
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Citations
Cited by
Coudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
Guest-to-Host Transmission of Structural Changes for Stimuli-Responsive Adsorption Property
Yanai, N., Uemura, T., Inoue, M., Matsuda, R., Fukushima, T., Tsujimoto, M., Isoda, S., & Kitagawa, S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2115713 · Cited by 369
Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
Recent Implementations of Molecular Photoswitches into Smart Materials and Biological Systems
Pianowski, Z. L. (2019) · Chemistry – A European Journal · doi:10.1002/chem.201805814 · Cited by 328
Gating effect for gas adsorption in microporous materials—mechanisms and applications
Chen, K., Mousavi, S. H., Singh, R., Snurr, R. Q., Li, G., & Webley, P. A. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00822f · Cited by 133
Metadata
- Authors
- Modrow, A., Zargarani, D., Herges, R., & Stock, N.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 40
- Issue
- 16
- Pages
- 4217
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2050078897
- Cited by
- 204
- References
- 0
- FWCI
- 7.14
- Type
- journal article
- Language
- en
- Open access
- green
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- Modrow, A., Zargarani, D., Herges, R., & Stock, N. (2011). The first porous MOF with photoswitchable linker molecules. Dalton Transactions. https://doi.org/10.1039/c0dt01629b
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