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Vegetable oil-based polymeric materials: synthesis, properties, and applications
Abstract
The use of vegetable oils as renewable raw materials for the synthesis of various monomers and polymeric materials is reviewed. Vegetable oils are generally considered to be the most important class of renewable resources, because of their ready availability and numerous applications. Recently, a variety of vegetable oil-based polymers have been prepared by free radical, cationic, olefin metathesis, and condensation polymerization. The polymers obtained display a wide range of thermophysical and mechanical properties from soft and flexible rubbers to hard and rigid plastics, which show promise as alternatives to petroleum-based plastics.
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“Biochar can be used as a support for catalytic nanoparticles to take advantage of their exceptional properties such as high electrical conductivity, chemical stability, having functional groups that can easily be tuned and unique surface properties (Cuong etal. 2019; Liu etal. 2015; Xia and Larock 2010).”
From Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater (2021) · cites this paper as Xia and Larock 2010
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“Another common renewable resource is plant oil, which is converted to fatty acids and glycerol for biodiesel and oleochemical production.16,25,81”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [81]
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Lei, Y., Wang, X.-L., Liu, B., Chen, L., & Wang, Y. (2020) · Chinese Chemical Letters · doi:10.1016/j.cclet.2020.06.015 · Cited by 31
Acik, G. (2020) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2020.109317 · Cited by 31
Anand, A., Kulkarni, R. D., Patil, C. K., & Gite, V. V. (2016) · RSC Advances · doi:10.1039/c5ra17202k · Cited by 32
Metadata
- Authors
- Xia, Y., & Larock, R. C.
- Affiliations
- Iowa State University (US)
- Corresponding author
- Larock, Richard C.
- ORCID
- Xia, Ying
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 12
- Issue
- 11
- Pages
- 1893
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1978517702
- Cited by
- 864
- References
- 136
- Citations by year
- 2026: 30 · 2025: 29 · 2024: 52 · 2023: 55 · 2022: 50 · 2021: 71 · 2020: 63 · 2019: 75 · 2018: 68 · 2017: 66 · 2016: 57 · 2015: 71 · 2014: 68 · 2013: 39 · 2012: 46
- FWCI
- 28.81
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- vegetable oils, vegetable oil-based polymers, renewable raw materials, radical polymerization, cationic polymerization, olefin metathesis, polycondensation, thermophysical properties, mechanical properties, biodegradable plastics
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