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Adsorption properties in high optical quality nanoZIF-8 thin films with tunable thickness
Abstract
We report processing of a thin film by chemical solution deposition of a microporous ZIF-8 nanoparticle dispersion. By using the drain and capillary regimes involved in the dip-coating process, we tuned the thickness of the films from 40 nm to 1 μm and controlled the packing of the nanoparticles on the substrate. The high optical quality thin films show a dual hierarchical porous structure from the micropores of the framework and the mesoporous interparticular voids. Moreover, vapor sorption properties of the microporous ZIF-8 based thin films have been evaluated by ellipsometric porosimetry. The hydrophobic films show alcohol, THF and hydrocarbon adsorption. Experiments for isopropanol/water separation have been carried out and the selective adsorption of the alcohol versus the water makes these thin films good candidates for vapor sensors.
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Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Cravillon, J., Nayuk, R., Springer, S., Feldhoff, A., Huber, K., & Wiebcke, M. (2011) · Chemistry of Materials · doi:10.1021/cm103571y · Cited by 916
Yusuf, V. F., Malek, N. I., & Kailasa, S. K. (2022) · ACS Omega · doi:10.1021/acsomega.2c05310 · Cited by 894
Liu, X., Li, Y., Zhu, G., Ban, Y., Xu, L., & Yang, W. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201104383 · Cited by 355
Li, W.-J., Tu, M., Cao, R., & Fischer, R. A. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta02118b · Cited by 283
Metadata
- Authors
- Demessence, A., Boissière, C., Grosso, D., Horcajada, P., Serre, C., Férey, G., Soler-Illia, G. J. A. A., & Sanchez, C.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2010
- Volume
- 20
- Issue
- 36
- Pages
- 7676
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2051420689
- Cited by
- 185
- References
- 0
- FWCI
- 8.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- Demessence, A., Boissière, C., Grosso, D., Horcajada, P., Serre, C., Férey, G., Soler-Illia, G. J. A. A., & Sanchez, C. (2010). Adsorption properties in high optical quality nanoZIF-8 thin films with tunable thickness. Journal of Materials Chemistry. https://doi.org/10.1039/c0jm00500b
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