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Achieving high specific charge capacitances in Fe3O4/reduced graphene oxide nanocomposites

Open access
Shi, Wenhui, Zhu, Jixin, Sim, Dao Hao, Tay, Yee Yan, Lu, Ziyang, Zhang, Xiaojun, Sharma, Yogesh, Srinivasan, Madhavi, Zhang, Hua, Hng, Huey Hoon, Yan, Qingyu·2011·Journal of Materials Chemistry

Abstract

We report a facile approach to synthesize nanocomposites with Fe3O4 nanopaticles (NPs) attached to reduced graphene oxide (rGO) sheets by a solvothermal process, which combines the growth of Fe3O4 NPs and the reduction of GOs in one single step. These Fe3O4/rGO nanocomposites were further used to fabricate thin film supercapacitor electrodes by using a spray deposition technique without the addition of insulating binders. It was found that the Fe3O4/rGO nanocomposites showed much higher specific capacitances than that of either pure rGO or pure Fe3O4 NPs. We further carried out electrochemical characterization of the Fe3O4/rGO nanocomposites with different Fe3O4 : rGO weight ratios (e.g. IFe3O4 : rGO) and showed that Fe3O4/rGO nanocomposites with IFe3O4 : rGO = 2.8 exhibited the highest specific capacitance of 480 F g−1 at a discharge current density of 5 A g−1 with the corresponding energy density of 67 W h kg−1 at a power density of 5506 W kg−1. These Fe3O4/rGO nanocomposites also showed stable cycling performance without any decrease in the specific capacitance after 1000 charge/discharge cycles.

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Metadata

Authors
Shi, W., Zhu, J., Sim, D. H., Tay, Y. Y., Lu, Z., Zhang, X., Sharma, Y., Srinivasan, M., Zhang, H., Hng, H. H., & Yan, Q.
Venue
Journal of Materials Chemistry
Published
2011
Volume
21
Issue
10
Pages
3422
ISSN
  • 0959-9428 (ISSN-L)
  • 1364-5501
OpenAlex
W1969812619
Cited by
470
References
1
FWCI
19.69
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Achieving high specific charge capacitances in Fe3O4/reduced graphene oxide nanocomposites. https://app.cochat.ai/papers/10.1039/c0jm03175e
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Shi, W., Zhu, J., Sim, D. H., Tay, Y. Y., Lu, Z., Zhang, X., Sharma, Y., Srinivasan, M., Zhang, H., Hng, H. H., & Yan, Q. (2011). Achieving high specific charge capacitances in Fe3O4/reduced graphene oxide nanocomposites. Journal of Materials Chemistry. https://doi.org/10.1039/c0jm03175e

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