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Graphene modified LiFePO4 cathode materials for high power lithium ion batteries
Abstract
Graphene-modified LiFePO4 composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO4 nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO4 primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO4 nanoparticles and graphene sheets was beneficial for Li+ diffusion. The composite cathode material could deliver a capacity of 70 mAh g−1 at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Cited by
Enhancing the performances of Li-ion batteries by carbon-coating: present and future
Li, H., & Zhou, H. (2012) · Chem. Commun. · doi:10.1039/c1cc14764a · Cited by 963
Li, W., Yang, Y., Zhang, G., & Zhang, Y.-W. (2015) · Nano Letters · doi:10.1021/nl504336h · Cited by 773
Graphene based metal and metal oxide nanocomposites: synthesis, properties and their applications
Khan, M., Tahir, M. N., Adil, S. F., Khan, H. U., Siddiqui, M. R. H., Al-warthan, A. A., & Tremel, W. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02240a · Cited by 709
Recent advances in the research of polyanion-type cathode materials for Li-ion batteries
Gong, Z., & Yang, Y. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00713g · Cited by 549
Carbon Nanomaterials in Different Dimensions for Electrochemical Energy Storage
Ni, J., & Li, Y. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600278 · Cited by 304
Metadata
- Authors
- Zhou, X., Wang, F., Zhu, Y., & Liu, Z.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 21
- Issue
- 10
- Pages
- 3353
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W1994120599
- Cited by
- 498
- References
- 1
- FWCI
- 41.89
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, X., Wang, F., Zhu, Y., & Liu, Z. (2011). Graphene modified LiFePO4 cathode materials for high power lithium ion batteries. Journal of Materials Chemistry. https://doi.org/10.1039/c0jm03287e
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
