The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
TEMPO-oxidized cellulose nanofibers
Abstract
Native wood celluloses can be converted to individual nanofibers 3-4 nm wide that are at least several microns in length, i.e. with aspect ratios>100, by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation and successive mild disintegration in water. Preparation methods and fundamental characteristics of TEMPO-oxidized cellulose nanofibers (TOCN) are reviewed in this paper. Significant amounts of C6 carboxylate groups are selectively formed on each cellulose microfibril surface by TEMPO-mediated oxidation without any changes to the original crystallinity (∼74%) or crystal width of wood celluloses. Electrostatic repulsion and/or osmotic effects working between anionically-charged cellulose microfibrils, the ζ-potentials of which are approximately -75 mV in water, cause the formation of completely individualized TOCN dispersed in water by gentle mechanical disintegration treatment of TEMPO-oxidized wood cellulose fibers. Self-standing TOCN films are transparent and flexible, with high tensile strengths of 200-300 MPa and elastic moduli of 6-7 GPa. Moreover, TOCN-coated poly(lactic acid) films have extremely low oxygen permeability. The new cellulose-based nanofibers formed by size reduction process of native cellulose fibers by TEMPO-mediated oxidation have potential application as environmentally friendly and new bio-based nanomaterials in high-tech fields.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Cellulose nanocrystals: chemistry, self-assembly, and applications
Habibi, Y., Lucia, L. A., & Rojas, O. J. (2010) · Chemical Reviews · doi:10.1021/cr900339w · Cited by 5,980
Pääkkö, M., Ankerfors, M., Kosonen, H., Nykänen, A., Ahola, S., Österberg, M., Ruokolainen, J., Laine, J., Larsson, P. T., Ikkala, O., et al. (2007) · Biomacromolecules · doi:10.1021/bm061215p · Cited by 1,962
Saito, T., Nishiyama, Y., Putaux, J.-L., Vignon, M., & Isogai, A. (2006) · Biomacromolecules · doi:10.1021/bm060154s · Cited by 1,796
Self-citationBeck-Candanedo, S., Roman, M., & Gray, D. G. (2005) · Biomacromolecules · doi:10.1021/bm049300p · Cited by 1,588
Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation
Fukuzumi, H., Saito, T., Iwata, T., Kumamoto, Y., & Isogai, A. (2009) · Biomacromolecules · doi:10.1021/bm801065u · Cited by 1,271
Self-citationEffect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose
DONG, X. M., REVOL, J.-F., & GRAY, D. G. (1998) · Cellulose · doi:10.1023/a:1009260511939 · Cited by 1,032
Rodlike cellulose microcrystals: Structure, properties and applications
de Souza Lima, M. M., & Borsali, R. (2004) · Macromolecular Rapid Communications · doi:10.1002/marc.200300268 · Cited by 894
Elastic modulus of single cellulose microfibrils from tunicate measured by atomic force microscopy
Iwamoto, S., Kai, W., Isogai, A., & Iwata, T. (2009) · Biomacromolecules · doi:10.1021/bm900520n · Cited by 754
Self-citationStrength and barrier properties of MFC films
Syverud, K., & Stenius, P. (2009) · Cellulose · doi:10.1007/s10570-008-9244-2 · Cited by 592
Topochemistry of carboxylated cellulose nanocrystals resulting from TEMPO-mediated oxidation
Montanari, S., Roumani, M., Heux, L., & Vignon, M. R. (2005) · Macromolecules · doi:10.1021/ma048396c · Cited by 398
Cited by
Developing fibrillated cellulose as a sustainable technological material
Li, T., Chen, C., Brozena, A. H., Zhu, J. Y., Xu, L., Driemeier, C., Dai, J., Rojas, O. J., Isogai, A., Wågberg, L., et al. (2021) · Nature · doi:10.1038/s41586-020-03167-7 · Cited by 1,674
Self-citationChen, Y., Zhang, L., Yang, Y., Pang, B., Xu, W., Duan, G., Jiang, S., & Zhang, K. (2021) · Advanced Materials · doi:10.1002/adma.202005569 · Cited by 721
Wood-based nanotechnologies toward sustainability
Jiang, F., Li, T., Li, Y., Zhang, Y., Gong, A., Dai, J., Hitz, E., Luo, W., & Hu, L. (2018) · Advanced Materials · doi:10.1002/adma.201703453 · Cited by 599
Chemically and mechanically isolated nanocellulose and their self-assembled structures
Jiang, F., & Hsieh, Y.-L. (2013) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2013.02.022 · Cited by 586
Chitin nanofibers: preparations, modifications, and applications
Ifuku, S., & Saimoto, H. (2012) · Nanoscale · doi:10.1039/c2nr30383c · Cited by 490
Metadata
- Authors
- Isogai, A., Saito, T., & Fukuzumi, H.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 3
- Issue
- 1
- Pages
- 71-85
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2110567375
- Cited by
- 3,179
- References
- 10
- FWCI
- 20.02
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: TEMPO-oxidized cellulose nanofibers. https://app.cochat.ai/papers/10.1039/c0nr00583e
- The paper
- Isogai, A., Saito, T., & Fukuzumi, H. (2011). TEMPO-oxidized cellulose nanofibers. Nanoscale. https://doi.org/10.1039/c0nr00583e
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
