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Application of a chiral metal–organic framework in enantioselective separation
Open accessAbstract
A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.
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Citations
Cited by
Adsorptive separation on metal–organic frameworks in the liquid phase
Van de Voorde, B., Bueken, B., Denayer, J., & De Vos, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00006d · Cited by 874
Chiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
CD-MOF: A Versatile Separation Medium
Hartlieb, K. J., Holcroft, J. M., Moghadam, P. Z., Vermeulen, N. A., Algaradah, M. M., Nassar, M. S., Botros, Y. Y., Snurr, R. Q., & Stoddart, J. F. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12860 · Cited by 323
Mass transfer in mesoporous materials: the benefit of microscopic diffusion measurement
Kärger, J., & Valiullin, R. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35326e · Cited by 280
Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation
Peng, Y., Gong, T., Zhang, K., Lin, X., Liu, Y., Jiang, J., & Cui, Y. (2014) · Nature Communications · doi:10.1038/ncomms5406 · Cited by 275
Metadata
- Authors
- Padmanaban, M., Müller, P., Lieder, C., Gedrich, K., Grünker, R., Bon, V., Senkovska, I., Baumgärtner, S., Opelt, S., Paasch, S., Brunner, E., Glorius, F., Klemm, E., & Kaskel, S.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 47
- Issue
- 44
- Pages
- 12089
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2162351863
- Cited by
- 168
- References
- 0
- FWCI
- 11.77
- Type
- journal article
- Language
- en
- Open access
- green
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- Padmanaban, M., Müller, P., Lieder, C., Gedrich, K., Grünker, R., Bon, V., Senkovska, I., Baumgärtner, S., Opelt, S., Paasch, S., Brunner, E., Glorius, F., Klemm, E., & Kaskel, S. (2011). Application of a chiral metal–organic framework in enantioselective separation. Chemical Communications. https://doi.org/10.1039/c1cc14893a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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