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Microporous metal–organic frameworks for acetylene storage and separation
Abstract
Acetylene is an important starting material in the petrochemical and electronic industry for various industrial and consumer products, and a promising alternative energy source for future acetylene fuel cell vehicles. Porous metal–organic frameworks have been demonstrated as very practical useful materials for acetylene storage and separation which might provide the solid resolution for the safe storage and transportation of acetylene. Because of the explosive nature of acetylene, strong interactions of the pore surfaces with acetylene are very important to realize high acetylene storage MOFs at room temperature and low pressure, which can be fulfilled by the immobilization of open metal sites. Microporous MOFs having high adsorption affinity and matchable pore size with acetylene molecules have been realized to exhibit high selective C2H2/CO2, C2H2/CH4 and C2H2/C2H4 separation.
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Cited by
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Porous metal-organic frameworks for gas storage and separation: Status and challenges
Li, H., Li, L., Lin, R.-B., Zhou, W., Zhang, Z., Xiang, S., & Chen, B. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100006 · Cited by 891
Self-citationHe, Y., Krishna, R., & Chen, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22858k · Cited by 674
Self-citationLuo, F., Yan, C., Dang, L., Krishna, R., Zhou, W., Wu, H., Dong, X., Han, Y., Hu, T.-L., O’Keeffe, M., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b02030 · Cited by 601
Self-citationLi, P., He, Y., Zhao, Y., Weng, L., Wang, H., Krishna, R., Wu, H., Zhou, W., O'Keeffe, M., Han, Y., et al. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201410077 · Cited by 423
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Metadata
- Authors
- Zhang, Z., Xiang, S., & Chen, B.
- Venue
- CrystEngComm
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 13
- Issue
- 20
- Pages
- 5983
- ISSN
- 1466-8033 (ISSN-L)
- OpenAlex
- W2130831264
- Cited by
- 167
- References
- 0
- FWCI
- 9.45
- Type
- journal article
- Language
- en
- Open access
- closed
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