The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Structure:function relationships in molecular spin-crossover complexes
Abstract
Spin-crossover compounds are becoming increasingly popular for device and sensor applications, and in soft materials, that make use of their switchable colour, paramagnetism and conductivity. The de novo design of new solid spin-crossover compounds with pre-defined switching properties is desirable for application purposes. This challenging problem of crystal engineering requires an understanding of how the temperature and cooperativity of a spin-transition are influenced by the structure of the bulk material. Towards that end, this critical review presents a survey of molecular spin-crossover compounds with good availability of crystallographic data. A picture is emerging that changes in molecular shape between the high- and low-spin states, and the ability of a lattice to accommodate such changes, can play an important role in determining the existence and the cooperativity of a thermal spin-transition in the solid state (198 references).
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Cites
The Cambridge Structural Database: a quarter of a million crystal structures and rising
Allen, F. H. (2002) · Acta Crystallographica Section B Structural Science · doi:10.1107/s0108768102003890 · Cited by 9,898
X-Seed — A Software Tool for Supramolecular Crystallography
Barbour, L. J. (2001) · Journal of Supramolecular Chemistry · doi:10.1016/s1472-7862(02)00030-8 · Cited by 2,565
Spin-Transition Polymers: From Molecular Materials Toward Memory Devices
Kahn, O., & Martinez, C. J. (1998) · Science · doi:10.1126/science.279.5347.44 · Cited by 2,272
Thermal and Optical Switching of Iron( II ) Complexes
Gütlich, P., Hauser, A., & Spiering, H. (1994) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199420241 · Cited by 2,146
Structure and chemistry of cytochrome p450
Denisov, I. G., Makris, T. M., Sligar, S. G., & Schlichting, I. (2005) · Chemical Reviews · doi:10.1021/cr0307143 · Cited by 2,106
Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material
Halder, G. J., Kepert, C. J., Moubaraki, B., Murray, K. S., & Cashion, J. D. (2002) · Science · doi:10.1126/science.1075948 · Cited by 1,569
Crystal Engineering: A Holistic View
Desiraju, G. R. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200700534 · Cited by 1,499
Spin crossover phenomena in Fe(ii) complexes
Gütlich, P., Garcia, Y., & Goodwin, H. A. (2000) · Chemical Society Reviews · doi:10.1039/b003504l · Cited by 1,162
Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials
Aromí, G., Barrios, L. A., Roubeau, O., & Gamez, P. (2011) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2010.10.038 · Cited by 989
Spin-state/stereochemical relationships in iron porphyrins: implications for the hemoproteins
Scheidt, W. R., & Reed, C. A. (1981) · Chemical Reviews · doi:10.1021/cr00046a002 · Cited by 622
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Emerging trends in spin crossover (SCO) based functional materials and devices
Senthil Kumar, K., & Ruben, M. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.03.024 · Cited by 845
Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
Ni, Z.-P., Liu, J.-L., Hoque, M. N., Liu, W., Li, J.-Y., Chen, Y.-C., & Tong, M.-L. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2016.12.002 · Cited by 448
Nandy, A., Duan, C., Taylor, M. G., Liu, F., Steeves, A. H., & Kulik, H. J. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00347 · Cited by 358
Spin crossover in discrete polynuclear iron(ii) complexes
Hogue, R. W., Singh, S., & Brooker, S. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00835j · Cited by 317
OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes
Ketkaew, R., Tantirungrotechai, Y., Harding, P., Chastanet, G., Guionneau, P., Marchivie, M., & Harding, D. J. (2021) · Dalton Transactions · doi:10.1039/d0dt03988h · Cited by 316
Metadata
- Authors
- Halcrow, M. A.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 40
- Issue
- 7
- Pages
- 4119
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2064311755
- Cited by
- 953
- References
- 42
- FWCI
- 1.27
- Type
- journal article
- Language
- en
- Open access
- closed
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