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Carbene-stabilized main group diatomic allotropes
Abstract
While transition metals are well known for assuming the formal oxidation state of zero in various compounds main group elements have rarely engaged in this practice. Recent reports of N-heterocyclic carbene-stabilized main group diatomic allotropes (i.e., Si(2), Ge(2), P(2), As(2)) denote a breakthrough of zero-oxidation state main group chemistry. This Perspective addresses the synthesis and characterization of these highly reactive main group molecules, with a particular emphasis on the very recent progress in the reactivity study of carbene-stabilized Si(2) and P(2).
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(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
Cited by
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
Melaimi, M., Jazzar, R., Soleilhavoup, M., & Bertrand, G. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702148 · Cited by 788
N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field
Wang, Y., & Robinson, G. H. (2014) · Inorganic Chemistry · doi:10.1021/ic502231m · Cited by 266
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Metadata
- Authors
- Wang, Y., & Robinson, G. H.
- Venue
- Dalton Trans.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 2
- Pages
- 337-345
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2068653676
- Cited by
- 240
- References
- 1
- FWCI
- 18.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Y., & Robinson, G. H. (2012). Carbene-stabilized main group diatomic allotropes. Dalton Trans. https://doi.org/10.1039/c1dt11165e
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