The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Bottom-up in situ formation of Fe3O4 nanocrystals in a porous carbon foam for lithium-ion battery anodes
Abstract
A facile and scalable process for the in situ formation of Fe3O4 nanocrystals in a pre-formed carbon foam (CF) (Fe3O4/CF) was developed, which involved impregnation of an aqueous iron nitrate solution onto CF followed by controlled thermal treatment in an inert atmosphere. N2adsorption/desorption and BET measurements showed that the CF was a mesoporous carbon with a high pore volume and specific surface area. Transmission electron microscopy, scanning electron microscopy, X-ray diffraction measurement, thermogravimetric analysis, and X-ray photoelectron spectroscopy (XPS) revealed that 5–50 nm Fe3O4 nanocrystals at a high loading of 78.7 wt% were formed preferentially in the confined pores of CF. When tested for anode material in a Li ion half-cell, the Fe3O4/CF composite was far superior to unsupported Fe3O4 nanocrystals, exhibiting significantly improved Coulombic efficiencies and cycling stability and achieving >780 mA h g−1 after 50 deep charge–discharge cycles with >95% cycling efficiency.
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Citations
Cites
Lithium Batteries: Status, Prospects and Future
Scrosati, B., & Garche, J. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.11.048 · Cited by 5,153
Cited by
Carbon-Encapsulated Fe3O4 Nanoparticles as a High-Rate Lithium Ion Battery Anode Material
He, C., Wu, S., Zhao, N., Shi, C., Liu, E., & Li, J. (2013) · ACS Nano · doi:10.1021/nn401059h · Cited by 981
Nanostructured Conversion-type Anode Materials for Advanced Lithium-Ion Batteries
Lu, Y., Yu, L., & Lou, X. W. (. (2018) · Chem · doi:10.1016/j.chempr.2018.01.003 · Cited by 783
Banerjee, A., Gokhale, R., Bhatnagar, S., Jog, J., Bhardwaj, M., Lefez, B., Hannoyer, B., & Ogale, S. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33798c · Cited by 324
Han, F., Li, D., Li, W., Lei, C., Sun, Q., & Lu, A. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201202254 · Cited by 306
Metadata
- Authors
- Yoon, T., Chae, C., Sun, Y.-K., Zhao, X., Kung, H. H., & Lee, J. K.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 21
- Issue
- 43
- Pages
- 17325
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2086147304
- Cited by
- 221
- References
- 1
- FWCI
- 16.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yoon, T., Chae, C., Sun, Y.-K., Zhao, X., Kung, H. H., & Lee, J. K. (2011). Bottom-up in situ formation of Fe3O4 nanocrystals in a porous carbon foam for lithium-ion battery anodes. Journal of Materials Chemistry. https://doi.org/10.1039/c1jm13450g
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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