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TiO2@carbon core/shell nanofibers: Controllable preparation and enhanced visible photocatalytic properties
Abstract
TiO(2)@carbon core/shell nanofibers (TiO(2)@C NFs) with different thinkness of carbon layers (from 2 to 8 nm) were fabricated by combining the electrospinning technique and hydrothermal method. The results showed that a uniform graphite carbon layer was formed around the electrospun TiO(2) nanofiber via C-O-Ti bonds. By adjusting the hydrothermal fabrication parameters, the thickness of carbon layer could be easily controlled. Furthermore, the TiO(2)@C NFs had remarkable light absorption in the visible region. The photocatalytic studies revealed that the TiO(2)@C NFs exhibited enhanced photocatalytic efficiency of photodegradation of Rhodamine B (RB) compared with the pure TiO(2) nanofibers under visible light irradiation, which might be attributed to high separation efficiency of photogenerated electrons and holes based on the synergistic effect between carbon as a sensitizer and TiO(2) with one dimension structure. Notably, the TiO(2)@C NFs could be easily recycled due to their one-dimensional nanostructural property.
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Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Cited by
A review of one-dimensional TiO2nanostructured materials for environmental and energy applications
Ge, M., Cao, C., Huang, J., Li, S., Chen, Z., Zhang, K.-Q., Al-Deyab, S. S., & Lai, Y. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta09323f · Cited by 930
Kumar, S. G., & Rao, K. S. R. K. (2015) · RSC Advances · doi:10.1039/c4ra13299h · Cited by 885
The recent development of efficient Earth-abundant transition-metal nanocatalysts
Wang, D., & Astruc, D. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00629a · Cited by 608
NIR-Responsive Photocatalytic Activity and Mechanism of NaYF4:Yb,Tm@TiO2 Core–Shell Nanoparticles
Tang, Y., Di, W., Zhai, X., Yang, R., & Qin, W. (2013) · ACS Catalysis · doi:10.1021/cs300808r · Cited by 393
Shao, L., Wang, Z. X., Zhang, Y. L., Jiang, Z. X., & Liu, Y. Y. (2014) · Journal of Membrane Science · doi:10.1016/j.memsci.2014.03.006 · Cited by 275
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Metadata
- Authors
- Zhang, P., Shao, C., Zhang, Z., Zhang, M., Mu, J., Guo, Z., & Liu, Y.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2011
- Volume
- 3
- Issue
- 7
- Pages
- 2943
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2094923758
- Cited by
- 205
- References
- 2
- FWCI
- 5.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, P., Shao, C., Zhang, Z., Zhang, M., Mu, J., Guo, Z., & Liu, Y. (2011). TiO2@carbon core/shell nanofibers: Controllable preparation and enhanced visible photocatalytic properties. Nanoscale. https://doi.org/10.1039/c1nr10269a
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