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Polyrotaxane metal–organic frameworks (PMOFs)
Abstract
Polyrotaxane metal-organic frameworks (PMOFs), a relatively rare branch of entangled networks, have received significant attention due to their unusual entanglement topologies. The PMOFs we described here are still at an early stage of development. This feature article summarizes the recent developments in structural types of PMOFs from our own group and others. We make some generalizations about the various classes of PMOFs, and develop the definitions and nomenclature of these entanglements, including classification into trivial and nontrivial polyrotaxanes, and limits on what constitutes a (nontrivial) polyrotaxane. Finally, the synthetic strategies toward the design and preparation of new PMOFs are elucidated.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
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Recent progress in metal-organic frameworks as active materials for supercapacitors
Wang, K.-B., Xun, Q., & Zhang, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2019.100025 · Cited by 474
Entangled Two-Dimensional Coordination Networks: A General Survey
Carlucci, L., Ciani, G., Proserpio, D. M., Mitina, T. G., & Blatov, V. A. (2014) · Chemical Reviews · doi:10.1021/cr500150m · Cited by 285
Metadata
- Authors
- Yang, J., Ma, J.-F., & Batten, S. R.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 48
- Issue
- 64
- Pages
- 7899
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1992361779
- Cited by
- 170
- References
- 1
- FWCI
- 15.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, J., Ma, J.-F., & Batten, S. R. (2012). Polyrotaxane metal–organic frameworks (PMOFs). Chemical Communications. https://doi.org/10.1039/c2cc33060a
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