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Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts
Abstract
Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to study short range order in heterometallic alloys for almost four decades. In this critical review, experimental, theoretical and data analytical approaches are revisited to examine their power, and limitations, in studies of bimetallic nanocatalysts. This article covers the basics of EXAFS experiments, data analysis, and modelling of nanoscale clusters. It demonstrates that, in the best case scenario, quantitative information about the nanocatalyst's size, shape, details of core-shell architecture, as well as static and dynamic disorder in metal-metal bond lengths can be obtained. The article also emphasizes the main challenge accompanying such insights: the need to account for the statistical nature of the EXAFS technique, and discusses corrective strategies.
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Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
Metal monolayer deposition by replacement of metal adlayers on electrode surfaces
Brankovic, S. R., Wang, J. X., & Adžić, R. R. (2001) · Surface Science · doi:10.1016/s0039-6028(00)01103-1 · Cited by 614
X-ray Absorption Spectroscopy of Low Temperature Fuel Cell Catalysts
Russell, A. E., & Rose, A. (2004) · Chemical Reviews · doi:10.1021/cr020708r · Cited by 303
Cited by
Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications
Gao, C., Low, J., Long, R., Kong, T., Zhu, J., & Xiong, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00840 · Cited by 1,050
Ni-based bimetallic heterogeneous catalysts for energy and environmental applications
De, S., Zhang, J., Luque, R., & Yan, N. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02002j · Cited by 786
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Metadata
- Authors
- Frenkel, A. I.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 24
- Pages
- 8163
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2081994669
- Cited by
- 321
- References
- 3
- FWCI
- 2.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Frenkel, A. I. (2012). Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts. Chemical Society Reviews. https://doi.org/10.1039/c2cs35174a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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