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Covalent chemistry on graphene
Abstract
The recent growth in graphene has witnessed the utilization of graphene as promising materials in a plethora of applications. The potential of graphene could be improved exponentially provided that the processability and band gap could be finely controlled. To this aim, chemical functionalization of graphene remains an important and fundamental approach. This tutorial review aims to provide a broad-based coverage on the recent solution-based functionalization methods of graphene in a concise and mechanistic manner. We focus on the reactions of the graphene sp(2) backbone, such as nucleophilic addition, cycloaddition, free radical additions, substitutions and rearrangements.
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Citations
Cites
Graphene-based nanomaterials and their electrochemistry
Pumera, M. (2010) · Chemical Society Reviews · doi:10.1039/c002690p · Cited by 1,117
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Bhattacharya, M. (2016) · Materials · doi:10.3390/ma9040262 · Cited by 747
Surface chemistry and catalysis confined under two-dimensional materials
Fu, Q., & Bao, X. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00424e · Cited by 532
Chemical functionalization and characterization of graphene-based materials
Bottari, G., Herranz, M. Á., Wibmer, L., Volland, M., Rodríguez-Pérez, L., Guldi, D. M., Hirsch, A., Martín, N., D'Souza, F., & Torres, T. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00229g · Cited by 441
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Li, X., & Zhi, L. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00871f · Cited by 377
Metadata
- Authors
- Chua, C. K., & Pumera, M.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 42
- Issue
- 8
- Pages
- 3222
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2131662926
- Cited by
- 359
- References
- 1
- FWCI
- 1.67
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.