The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
Open accessAbstract
The synthesis, activation, and heats of CO(2) adsorption for the known members of the M(3)(BTC)(2) (HKUST-1) isostructural series (M = Cr, Fe, Ni, Zn, Ni, Cu, Mo) were investigated to gain insight into the impact of CO(2)-metal interactions for CO(2) storage/separation applications. With the use of modified syntheses and activation procedures, improved BET surface areas were obtained for M = Ni, Mo, and Ru. The zero-coverage isosteric heats of CO(2) adsorption were measured for the Cu, Cr, Ni, Mo, and Ru analogues and gave values consistent with those reported for MOFs containing coordinatively unsaturated metal sites, but lower than for amine functionalized materials. Notably, the Ni and Ru congeners exhibited the highest CO(2) affinities in the studied series. These behaviors were attributed to the presence of residual guest molecules in the case of Ni(3)(BTC)(2)(Me(2)NH)(2)(H(2)O) and the increased charge of the dimetal secondary building unit in [Ru(3)(BTC)(2)][BTC](0.5).
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Cites
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
CO2 capture by solid adsorbents and their applications: current status and new trends
Wang, Q., Luo, J., Zhong, Z., & Borgna, A. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00064g · Cited by 1,611
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Sumida, K., Horike, S., Kaye, S. S., Herm, Z. R., Queen, W. L., Brown, C. M., Grandjean, F., Long, G. J., Dailly, A., & Long, J. R. (2010) · Chemical Science · doi:10.1039/c0sc00179a · Cited by 347
Cited by
Metal‐Organic Framework‐Based Nanomaterials for Electrocatalysis
Mahmood, A., Guo, W., Tabassum, H., & Zou, R. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600423 · Cited by 632
Grand Challenges and Future Opportunities for Metal–Organic Frameworks
Hendon, C. H., Rieth, A. J., Korzyński, M. D., & Dincă, M. (2017) · ACS Central Science · doi:10.1021/acscentsci.7b00197 · Cited by 434
Self-citationMetal–organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy
Chaemchuen, S., Kabir, N. A., Zhou, K., & Verpoort, F. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60244c · Cited by 416
Liao, P.-Q., Chen, H., Zhou, D.-D., Liu, S.-Y., He, C.-T., Rui, Z., Ji, H., Zhang, J.-P., & Chen, X.-M. (2015) · Energy & Environmental Science · doi:10.1039/c4ee02717e · Cited by 270
Metadata
- Authors
- Wade, C. R., & Dincă, M.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 26
- Pages
- 7931
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W1524197272
- Cited by
- 210
- References
- 4
- FWCI
- 7.87
- Type
- journal article
- Language
- en
- Open access
- green
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- Wade, C. R., & Dincă, M. (2012). Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru). Dalton Transactions. https://doi.org/10.1039/c2dt30372h
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