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Synthesis of a honeycomb-like Cu-based metal–organic framework and its carbon dioxide adsorption behaviour

Sanz, Raúl, Martínez, Fernando, Orcajo, Gisela, Wojtas, Lukasz, Briones, David·2013·Dalton Trans.

Abstract

Herein, we report on a new Cu-based MOF material, Cu(2)(dhtp), structurally homologous to the honeycomb-like M(2)(dhtp) series. This has been crystallized under solvothermal conditions using copper nitrate and 2,5-dihydroxyterephthalic acid as an organic linker, being the nature of the co-solvent in the synthesis media an important variable over the final physical properties of the material. The presence of isopropanol as a co-solvent leads to the formation of a pure crystalline phase with textural properties comparable to M(2)(dhtp) homologues. The interesting results in CO(2) adsorption properties of this new material, especially its isosteric heat of adsorption, make it a suitable MOF to be further evaluated under real conditions of industrial CO(2) capture.

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Metadata

Authors
Sanz, R., Martínez, F., Orcajo, G., Wojtas, L., & Briones, D.
Venue
Dalton Trans.
Published
2013
Volume
42
Issue
7
Pages
2392-2398
ISSN
  • 1477-9226 (ISSN-L)
  • 1477-9234
OpenAlex
W2133332294
Cited by
202
References
2
FWCI
5.94
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synthesis of a honeycomb-like Cu-based metal–organic framework and its carbon dioxide adsorption behaviour. https://app.cochat.ai/papers/10.1039/c2dt32138f
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Sanz, R., Martínez, F., Orcajo, G., Wojtas, L., & Briones, D. (2013). Synthesis of a honeycomb-like Cu-based metal–organic framework and its carbon dioxide adsorption behaviour. Dalton Trans. https://doi.org/10.1039/c2dt32138f

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