The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Reviving rechargeable lithium metal batteries: enabling next-generation high-energy and high-power cells
Abstract
Herein reported is a fundamentally new strategy for reviving rechargeable lithium (Li) metal batteries and enabling the emergence of next-generation safe batteries featuring a graphene-supported Li metal anode, including the highly promising Li–sulfur, Li–air, and Li–graphene cells with exceptionally high energy or power densities. All the Li metal anode-based batteries suffer from a high propensity to form Li dendrites (tree-like structures) at the anode upon repeated discharges/charges. A dendrite could eventually penetrate through the separator to reach the cathode, causing internal short-circuiting and even explosion, the main reason for the battery industry to abandon rechargeable lithium metal batteries in the early 1990s. By implementing graphene sheets to increase the anode surface areas, one can significantly reduce the anode current density, thereby dramatically prolonging the dendrite initiation time and decreasing the growth rate of a dendrite, if ever initiated, possibly by a factor of up to 1010 and 105, respectively.
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Cites
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Chemical methods for the production of graphenes
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A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
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Graphene-Based Supercapacitor with an Ultrahigh Energy Density
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Self-citationYoo, E., Kim, J., Hosono, E., Zhou, H.-S., Kudo, T., & Honma, I. (2008) · Nano Letters · doi:10.1021/nl800957b · Cited by 2,921
Mechanisms for Lithium Insertion in Carbonaceous Materials
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Cited by
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Lithium metal anodes for rechargeable batteries
Xu, W., Wang, J., Ding, F., Chen, X., Nasybulin, E., Zhang, Y., & Zhang, J.-G. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee40795k · Cited by 4,704
Rechargeable Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., Chung, S.-H., Zu, C., & Su, Y.-S. (2014) · Chemical Reviews · doi:10.1021/cr500062v · Cited by 4,665
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
Ding, F., Xu, W., Graff, G. L., Zhang, J., Sushko, M. L., Chen, X., Shao, Y., Engelhard, M. H., Nie, Z., Xiao, J., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja312241y · Cited by 2,107
Advancing Lithium Metal Batteries
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Metadata
- Authors
- Zhamu, A., Chen, G., Liu, C., Neff, D., Fang, Q., Yu, Z., Xiong, W., Wang, Y., Wang, X., & Jang, B. Z.
- Venue
- Energy Environ. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 2
- Pages
- 5701-5707
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2159156446
- Cited by
- 300
- References
- 38
- FWCI
- 6.46
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhamu, A., Chen, G., Liu, C., Neff, D., Fang, Q., Yu, Z., Xiong, W., Wang, Y., Wang, X., & Jang, B. Z. (2012). Reviving rechargeable lithium metal batteries: enabling next-generation high-energy and high-power cells. Energy Environ. Sci. https://doi.org/10.1039/c2ee02911a
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