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Cited by 158

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Visible-light-driven nonsacrificial water oxidation over tungsten trioxide powder modified with two different cocatalysts

Ma, Su Su Khine, Maeda, Kazuhiko, Abe, Ryu, Domen, Kazunari·2012·Energy & Environmental Science

Abstract

Tungsten trioxide (WO3) powder was studied as a photocatalyst for water oxidation under visible light (λ > 420 nm). WO3 modified with nanoparticulate Pt species (more specifically, PtOx) as cocatalysts is capable of photocatalyzing water oxidation under visible light in the presence of iodate (IO3−) ions as an electron acceptor under near-neutral pH conditions (pH ≈ 5.9). When PtOx/WO3 was further modified with a very small amount (0.001 wt%) of a metal oxide (e.g., MnOx, CoOx, RuO2 or IrO2) as a secondary cocatalyst, the water oxidation activity was improved. Among the metal oxide cocatalysts examined, RuO2 was found to give the highest performance, with an apparent quantum yield of 14.4% at 420 nm. The results of photocatalytic reactions and photoelectrochemical analyses suggest that the main roles of the loaded PtOx and RuO2 on WO3 are to promote the reduction of IO3− and water oxidation, respectively.

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Metadata

Authors
Ma, S. S. K., Maeda, K., Abe, R., & Domen, K.
Venue
Energy & Environmental Science
Published
2012
Volume
5
Issue
8
Pages
8390
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W2029198215
Cited by
158
References
1
FWCI
5.71
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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