The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Visible-light-driven nonsacrificial water oxidation over tungsten trioxide powder modified with two different cocatalysts
Abstract
Tungsten trioxide (WO3) powder was studied as a photocatalyst for water oxidation under visible light (λ > 420 nm). WO3 modified with nanoparticulate Pt species (more specifically, PtOx) as cocatalysts is capable of photocatalyzing water oxidation under visible light in the presence of iodate (IO3−) ions as an electron acceptor under near-neutral pH conditions (pH ≈ 5.9). When PtOx/WO3 was further modified with a very small amount (0.001 wt%) of a metal oxide (e.g., MnOx, CoOx, RuO2 or IrO2) as a secondary cocatalyst, the water oxidation activity was improved. Among the metal oxide cocatalysts examined, RuO2 was found to give the highest performance, with an apparent quantum yield of 14.4% at 420 nm. The results of photocatalytic reactions and photoelectrochemical analyses suggest that the main roles of the loaded PtOx and RuO2 on WO3 are to promote the reduction of IO3− and water oxidation, respectively.
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Citations
Cites
Photocatalytic Water Splitting: Recent Progress and Future Challenges
Maeda, K., & Domen, K. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1007966 · Cited by 2,739
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Cited by
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
Moniz, S. J. A., Shevlin, S. A., Martin, D. J., Guo, Z.-X., & Tang, J. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03271c · Cited by 2,363
Tungsten Oxides for Photocatalysis, Electrochemistry, and Phototherapy
Huang, Z., Song, J., Pan, L., Zhang, X., Wang, L., & Zou, J. (2015) · Advanced Materials · doi:10.1002/adma.201501217 · Cited by 608
Metadata
- Authors
- Ma, S. S. K., Maeda, K., Abe, R., & Domen, K.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 8
- Pages
- 8390
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2029198215
- Cited by
- 158
- References
- 1
- FWCI
- 5.71
- Type
- journal article
- Language
- en
- Open access
- closed
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