The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation
Open accessAbstract
As synthesised ZIF-8 nanoparticles (size ∼ 60 nm and specific surface area ∼ 1300–1600 m2 g−1) were directly incorporated into a model polymer matrix (Matrimid® 5218) by solution mixing. This produces flexible transparent membranes with excellent dispersion of nanoparticles (up to loadings of 30 wt%) with good adhesion within the polymer matrix, as confirmed by scanning electron microscopy, dynamic mechanical thermal analysis and gas sorption studies. Pure gas (H2, CO2, O2, N2 and CH4) permeation tests showed enhanced permeability of the mixed matrix membrane with negligible losses in selectivity. Positron annihilation lifetime spectroscopy (PALS) indicated that an increase in the free volume of the polymer with ZIF-8 loading together with the free diffusion of gas through the cages of ZIF-8 contributed to an increase in gas permeability of the composite membrane. The gas transport properties of the composite membranes were well predicted by a Maxwell model whilst the processing strategy reported can be extended to fabricate other polymer nanocomposite membranes intended for a wide range of emerging energy applications.
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Citations
Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Self-citationTan, J. C., Bennett, T. D., & Cheetham, A. K. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1003205107 · Cited by 552
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Cited by
Metal–organic frameworks for membrane-based separations
Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820
Membrane gas separation technologies for biogas upgrading
Chen, X. Y., Vinh-Thang, H., Ramirez, A. A., Rodrigue, D., & Kaliaguine, S. (2015) · RSC Advances · doi:10.1039/c5ra00666j · Cited by 503
Zhu, Y., Ciston, J., Zheng, B., Miao, X., Czarnik, C., Pan, Y., Sougrat, R., Lai, Z., Hsiung, C.-E., Yao, K., et al. (2017) · Nature Materials · doi:10.1038/nmat4852 · Cited by 429
Wang, H., He, S., Qin, X., Li, C., & Li, T. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b10138 · Cited by 325
Metadata
- Authors
- Song, Q., Nataraj, S. K., Roussenova, M. V., Tan, J. C., Hughes, D. J., Li, W., Bourgoin, P., Alam, M. A., Cheetham, A. K., Al-Muhtaseb, S. A., & Sivaniah, E.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 8
- Pages
- 8359
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2138016416
- Cited by
- 744
- References
- 4
- FWCI
- 59.29
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Song, Q., Nataraj, S. K., Roussenova, M. V., Tan, J. C., Hughes, D. J., Li, W., Bourgoin, P., Alam, M. A., Cheetham, A. K., Al-Muhtaseb, S. A., & Sivaniah, E. (2012). Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation. Energy & Environmental Science. https://doi.org/10.1039/c2ee21996d
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