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Three-dimensionally ordered macroporous FeF3 and its in situ homogenous polymerization coating for high energy and power density lithium ion batteries
Abstract
A new hybrid nanostructure composed of three-dimensionally ordered macroporous (3DOM) FeF3 and an homogenous coating of poly(3, 4-ethylenedioxythiophene) (PEDOT) is successfully synthesized using polystyrene (PS) colloidal crystals as hard template, and the coating of PEDOT is achieved through a novel in situ polymerization method. The special nanostructure provides a three-dimensional, continuous, and fast electronic and ionic path in the electrode. Surprisingly, the advantageous combination of 3DOM structure and homogenous coating of PEDOT endows the as-prepared hybrid nanostructures with a stable and high reversible discharge capacity up to 210 mA h g−1 above 2.0 V at room temperature (RT), and a good rate capability of 120 mA h g−1 at a high current density of 1 A g−1, which opens up new opportunities in the development of high performance next-generation lithium-ion batteries (LIBs).
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Cited by
Conversion Reaction‐Based Oxide Nanomaterials for Lithium Ion Battery Anodes
Yu, S., Lee, S. H., Lee, D. J., Sung, Y., & Hyeon, T. (2016) · Small · doi:10.1002/smll.201502299 · Cited by 499
Armstrong, E., & O'Dwyer, C. (2015) · Journal of Materials Chemistry C · doi:10.1039/c5tc01083g · Cited by 342
Synthesis of MoS2 nanosheet–graphene nanosheet hybrid materials for stable lithium storage
Zhou, X., Wan, L.-J., & Guo, Y.-G. (2013) · Chemical Communications · doi:10.1039/c3cc38780a · Cited by 304
Metadata
- Authors
- Ma, D.-L., Cao, Z.-Y., Wang, H.-G., Huang, X.-L., Wang, L.-M., & Zhang, X.-B.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 9
- Pages
- 8538
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2140643043
- Cited by
- 221
- References
- 0
- FWCI
- 16.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ma, D.-L., Cao, Z.-Y., Wang, H.-G., Huang, X.-L., Wang, L.-M., & Zhang, X.-B. (2012). Three-dimensionally ordered macroporous FeF3 and its in situ homogenous polymerization coating for high energy and power density lithium ion batteries. Energy & Environmental Science. https://doi.org/10.1039/c2ee22568a
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