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Tunable copper-catalyzed chemoselective hydrogenolysis of biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran
Abstract
Direct conversion of γ-valerolactone, which is one of the most significant cellulose-derived compounds, into 1,4-pentanediol was carried out by chemoselective hydrogenolysis catalyzed by a simple yet versatile copper–zirconia catalyst. Depending on the reaction conditions, 2-methyltetrahydrofuran could also be obtained in excellent yields.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Cited by
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Furfural: a renewable and versatile platform molecule for the synthesis of chemicals and fuels
Mariscal, R., Maireles-Torres, P., Ojeda, M., Sádaba, I., & López Granados, M. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02666k · Cited by 1,642
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
Li, H., Fang, Z., Smith, R. L., & Yang, S. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2016.04.004 · Cited by 284
Metadata
- Authors
- Du, X.-L., Bi, Q.-Y., Liu, Y.-M., Cao, Y., He, H.-Y., & Fan, K.-N.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 14
- Issue
- 4
- Pages
- 935
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2015029876
- Cited by
- 211
- References
- 2
- FWCI
- 7.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- Du, X.-L., Bi, Q.-Y., Liu, Y.-M., Cao, Y., He, H.-Y., & Fan, K.-N. (2012). Tunable copper-catalyzed chemoselective hydrogenolysis of biomass-derived γ-valerolactone into 1,4-pentanediol or 2-methyltetrahydrofuran. Green Chemistry. https://doi.org/10.1039/c2gc16599f
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
