The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Synergistic catalysis: A powerful synthetic strategy for new reaction development
Open accessAbstract
Synergistic catalysis is a synthetic strategy wherein both the nucleophile and the electrophile are simultaneously activated by two separate and distinct catalysts to afford a single chemical transformation. This powerful catalysis strategy leads to several benefits, specifically synergistic catalysis can (i) introduce new, previously unattainable chemical transformations, (ii) improve the efficiency of existing transformations, and (iii) create or improve catalytic enantioselectivity where stereocontrol was previously absent or challenging. This perspective aims to highlight these benefits using many of the successful examples of synergistic catalysis found in the literature.
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Cites
Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Sonogashira, K., Tohda, Y., & Hagihara, N. (1975) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)91094-3 · Cited by 5,208
Visible light photoredox catalysis: applications in organic synthesis
Narayanam, J. M. R., & Stephenson, C. R. J. (2011) · Chem. Soc. Rev. · doi:10.1039/b913880n · Cited by 4,161
Asymmetric Transition Metal-Catalyzed Allylic Alkylations
Trost, B. M., & Vranken, D. L. V. (1996) · Chemical Reviews · doi:10.1021/cr9409804 · Cited by 3,205
The Sonogashira Reaction: A Booming Methodology in Synthetic Organic Chemistry
Chinchilla, R., & Nájera, C. (2007) · Chemical Reviews · doi:10.1021/cr050992x · Cited by 2,974
Mukherjee, S., Yang, J. W., Hoffmann, S., & List, B. (2007) · Chemical Reviews · doi:10.1021/cr0684016 · Cited by 2,849
New Chiral Phosphorus Ligands for Enantioselective Hydrogenation
Tang, W., & Zhang, X. (2003) · Chemical Reviews · doi:10.1021/cr020049i · Cited by 2,570
Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
Nicewicz, D. A., & MacMillan, D. W. C. (2008) · Science · doi:10.1126/science.1161976 · Cited by 2,489
Self-citationRecent advances in Sonogashira reactions
Chinchilla, R., & Nájera, C. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15071e · Cited by 1,541
Lanthanide Complexes in Multifunctional Asymmetric Catalysis
Shibasaki, M., & Yoshikawa, N. (2002) · Chemical Reviews · doi:10.1021/cr010297z · Cited by 1,199
Coinage Metal−N-Heterocyclic Carbene Complexes
Lin, J. C. Y., Huang, R. T. W., Lee, C. S., Bhattacharyya, A., Hwang, W. S., & Lin, I. J. B. (2009) · Chemical Reviews · doi:10.1021/cr8005153 · Cited by 1,036
Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis
Nagib, D. A., Scott, M. E., & MacMillan, D. W. C. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9053338 · Cited by 988
Self-citationMetal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery
Park, Y. J., Park, J.-W., & Jun, C.-H. (2008) · Accounts of Chemical Research · doi:10.1021/ar700133y · Cited by 929
Doucet, H., & Hierso, J. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200602761 · Cited by 854
Palladium catalyzed synthesis of aryl, heterocyclic and vinylic acetylene derivatives
Dieck, H. A., & HECK, F. R. (1975) · Journal of Organometallic Chemistry · doi:10.1016/s0022-328x(00)94049-x · Cited by 749
Metal‐Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light
Neumann, M., Füldner, S., König, B., & Zeitler, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201002992 · Cited by 715
Mukherjee, S., & List, B. (2007) · Journal of the American Chemical Society · doi:10.1021/ja074678r · Cited by 618
Two‐Metal Ion Catalysis in Enzymatic Acyl‐ and Phosphoryl‐Transfer Reactions
Sträter, N., Lipscomb, W. N., Klabunde, T., & Krebs, B. (1996) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199620241 · Cited by 611
Chiral N-heterocyclic carbene-transition metal complexes in asymmetric catalysis
Perry, M. C., & Burgess, K. (2003) · Tetrahedron: Asymmetry · doi:10.1016/s0957-4166(03)00037-5 · Cited by 544
An Efficient and Chemoselective Iron Catalyst for the Hydrogenation of Ketones
Casey, C. P., & Guan, H. (2007) · Journal of the American Chemical Society · doi:10.1021/ja071159f · Cited by 539
Kingsbury, W. D., Boehm, J. C., Jakas, D. R., Holden, K. G., Hecht, S. M., Gallagher, G., Caranfa, M. J., McCabe, F. L., Faucette, L. F., Johnson, R. K., et al. (1991) · Journal of Medicinal Chemistry · doi:10.1021/jm00105a017 · Cited by 518
Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis
Shih, H.-W., Vander Wal, M. N., Grange, R. L., & MacMillan, D. W. C. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106593m · Cited by 509
Self-citationRecent Progress in Asymmetric Bifunctional Catalysis Using Multimetallic Systems
Shibasaki, M., Kanai, M., Matsunaga, S., & Kumagai, N. (2009) · Accounts of Chemical Research · doi:10.1021/ar9000108 · Cited by 495
Dual catalysis: combining photoredox and Lewis base catalysis for direct Mannich reactions
Rueping, M., Vila, C., Koenigs, R. M., Poscharny, K., & Fabry, D. C. (2011) · Chem. Commun. · doi:10.1039/c0cc04539j · Cited by 384
Allen, A., & MacMillan, D. W. C. (2010) · Journal of the American Chemical Society · doi:10.1021/ja100748y · Cited by 374
Self-citationKoller, R., Stanek, K., Stolz, D., Aardoom, R., Niedermann, K., & Togni, A. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200900974 · Cited by 313
Organocatalysis in Radical Chemistry. Enantioselective α-Oxyamination of Aldehydes
Sibi, M. P., & Hasegawa, M. (2007) · Journal of the American Chemical Society · doi:10.1021/ja069245n · Cited by 301
LI, C. ‐., & Wei, C. (2002) · Chemical Communications · doi:10.1039/b108851n · Cited by 296
Organocatalytic Asymmetric Alkylation of Aldehydes by SN1‐Type Reaction of Alcohols
Cozzi, P. G., Benfatti, F., & Zoli, L. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200805423 · Cited by 258
Conrad, J. C., Kong, J., Laforteza, B. N., & MacMillan, D. W. C. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9026902 · Cited by 255
Self-citationNakoji, M., Kanayama, T., Okino, T., & Takemoto, Y. (2001) · Organic Letters · doi:10.1021/ol016567h · Cited by 233
HSAB matching and mismatching in selective catalysis and synthesis
Woodward, S. (2002) · Tetrahedron · doi:10.1016/s0040-4020(01)01200-5 · Cited by 135
Fukuzumi, S., Mochizuki, S., & Tanaka, T. (1990) · The Journal of Physical Chemistry · doi:10.1021/j100365a039 · Cited by 132
Grignard type reaction via C–H bond activation in water
Wei, C., & LI, C. ‐. (2002) · Green Chemistry · doi:10.1039/b110102c · Cited by 106
Xia, A., Xu, D., Luo, S., Jiang, J., Tang, J., Wang, Y., & Xu, Z. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200902540 · Cited by 70
Bifunctional acid—base catalysis by imidazole groups in enzyme mimics
Breslow, R. (1994) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(94)00046-8 · Cited by 60
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Huang, Y.-B., Liang, J., Wang, X.-S., & Cao, R. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00250a · Cited by 1,908
Organocatalysis in Inert C–H Bond Functionalization
Qin, Y., Zhu, L., & Luo, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00657 · Cited by 785
Stereodivergence in Asymmetric Catalysis
Krautwald, S., & Carreira, E. M. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13340 · Cited by 527
Noble, A., McCarver, S. J., & MacMillan, D. W. C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511913h · Cited by 448
Self-citationEfficient valorization of biomass to biofuels with bifunctional solid catalytic materials
Li, H., Fang, Z., Smith, R. L., & Yang, S. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2016.04.004 · Cited by 284
Metadata
- Authors
- Allen, A. E., & MacMillan, D. W. C.
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 3
- Issue
- 3
- Pages
- 633
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2125106638
- Cited by
- 1,201
- References
- 36
- FWCI
- 41.70
- Type
- journal article
- Language
- en
- Open access
- green
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