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Enhanced isosteric heat, selectivity, and uptake capacity of CO2adsorption in a metal-organic framework by impregnated metal ions
Abstract
We demonstrate by experimental and theoretical studies that the impregnation of various metal ions such as Li+, Mg2+, Ca2+, Co2+, and Ni2+ in the pores of an anionic MOF, [Zn3(TCPT)2(HCOO)][NH2(CH3)2] (SNU-100′) significantly enhances isosteric heat, selectivity, and uptake capacity of the CO2 adsorption in the MOF. Due to the electrostatic interactions between CO2 and the extra-framework metal ions, the isosteric heats of CO2 adsorption are increased to 37.4–34.5 kJ mol−1 and the adsorption selectivities of CO2 over N2 at room temperature are increased to 40.4–31.0, compared with those (29.3 kJ mol−1 and 25.5, respectively) of the parent MOF (SNU-100′) containing [NH2(CH3)2]+ cations.
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Millward, A. R., & Yaghi, O. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0570032 · Cited by 2,876
Cited by
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications
Lin, Z.-J., Lü, J., Hong, M., & Cao, R. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60483g · Cited by 874
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Ionic metal-organic frameworks (iMOFs): Design principles and applications
Karmakar, A., Desai, A. V., & Ghosh, S. K. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.08.007 · Cited by 308
Metadata
- Authors
- Park, H. J., & Suh, M. P.
- Venue
- Chem. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 4
- Issue
- 2
- Pages
- 685-690
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- OpenAlex
- W2094824976
- Cited by
- 166
- References
- 1
- FWCI
- 9.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- Park, H. J., & Suh, M. P. (2013). Enhanced isosteric heat, selectivity, and uptake capacity of CO2adsorption in a metal-organic framework by impregnated metal ions. Chem. Sci. https://doi.org/10.1039/c2sc21253f
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