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Facile C–H activation by lutetium–methyl and lutetium–hydride complexes
Abstract
Bis(pentamethylcyclopentadienyl)lutetium complexes Lu(η5-C5Me5)2R (R = Me, H) react at 20–50 °C in hydrocarbon solvents with benzene, pyridine, the ylide CH2PPh3, and tetramethylsilane to give stable, isolatable products of C–H activation, i.e. metallation at a carbon of the reagent with extrusion of R–H.
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Citations
Cited by
Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry
Copéret, C., Chabanas, M., Petroff Saint‐Arroman, R., & Basset, J. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200390072 · Cited by 1,079
C−H Bond Activation and Organometallic Intermediates on Isolated Metal Centers on Oxide Surfaces
Coperet, C. (2010) · Chemical Reviews · doi:10.1021/cr900122p · Cited by 434
Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C5Me5)3M
Evans, W. J., & Davis, B. L. (2002) · Chemical Reviews · doi:10.1021/cr010298r · Cited by 314
The organometallic Chemistry of the lanthanide elements in low oxidation states
Evans, W. J. (1987) · Polyhedron · doi:10.1016/s0277-5387(00)80921-3 · Cited by 314
σ-Bond Metathesis: A 30-Year Retrospective
Waterman, R. (2013) · Organometallics · doi:10.1021/om400760k · Cited by 302
Metadata
- Authors
- Watson, P. L.
- Venue
- J. Chem. Soc., Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1983
- Issue
- 6
- Pages
- 276-277
- ISSN
- 0022-4936 (ISSN-L)
- OpenAlex
- W2016673928
- Cited by
- 226
- References
- 0
- FWCI
- 10.88
- Type
- journal article
- Language
- en
- Open access
- closed
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- Watson, P. L. (1983). Facile C–H activation by lutetium–methyl and lutetium–hydride complexes. J. Chem. Soc., Chem. Commun. https://doi.org/10.1039/c39830000276
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