The DOI matches its Crossref record; 78 of the 78 references it cites were found in a registry or an index.
Combined theoretical and experimental analysis of processes determining cathode performance in solid oxide fuel cells
Abstract
Solid oxide fuel cells (SOFC) are under intensive investigation since the 1980's as these devices open the way for ecologically clean direct conversion of the chemical energy into electricity, avoiding the efficiency limitation by Carnot's cycle for thermochemical conversion. However, the practical development of SOFC faces a number of unresolved fundamental problems, in particular concerning the kinetics of the electrode reactions, especially oxygen reduction reaction. We review recent experimental and theoretical achievements in the current understanding of the cathode performance by exploring and comparing mostly three materials: (La,Sr)MnO3 (LSM), (La,Sr)(Co,Fe)O3 (LSCF) and (Ba,Sr)(Co,Fe)O3 (BSCF). Special attention is paid to a critical evaluation of advantages and disadvantages of BSCF, which shows the best cathode kinetics known so far for oxides. We demonstrate that it is the combined experimental and theoretical analysis of all major elementary steps of the oxygen reduction reaction which allows us to predict the rate determining steps for a given material under specific operational conditions and thus control and improve SOFC performance.
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Cited by
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Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers
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Metadata
- Authors
- Kuklja, M. M., Kotomin, E. A., Merkle, R., Mastrikov, Y. A., & Maier, J.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 15
- Issue
- 15
- Pages
- 5443
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2034093414
- Cited by
- 279
- References
- 78
- FWCI
- 12.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kuklja, M. M., Kotomin, E. A., Merkle, R., Mastrikov, Y. A., & Maier, J. (2013). Combined theoretical and experimental analysis of processes determining cathode performance in solid oxide fuel cells. Physical Chemistry Chemical Physics. https://doi.org/10.1039/c3cp44363a
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