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A microporous luminescent europium metal–organic framework for nitro explosive sensing
Abstract
A microporous metal–organic framework (MOF) Eu3(MFDA)4(NO3)(DMF)3 (1, H2MFDA = 9,9-dimethylfluorene-2,7-dicarboxylic acid) has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. 1 is a three-dimensional coordination polymer with pcu type rod-packing structure, through which 1D rhombic channels penetrate. The solvent-free form 1a could be obtained by direct heating of 1. Both 1 and 1a exhibit high intensity red light emissions with high quantum yields and long luminescence lifetimes when excited at 336 nm at ambient temperature. The potential of 1a for nitro explosive sensing is studied through luminescence quenching experiments, which show that 1a is a potential luminescent sensory material for nitro explosives.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Liu, J.-Q., Luo, Z.-D., Pan, Y., Kumar Singh, A., Trivedi, M., & Kumar, A. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213145 · Cited by 508
Ma, D., Li, B., Zhou, X., Zhou, Q., Liu, K., Zeng, G., Li, G., Shi, Z., & Feng, S. (2013) · Chemical Communications · doi:10.1039/c3cc44546a · Cited by 358
Self-citationMOF based luminescence tuning and chemical/physical sensing
Müller-Buschbaum, K., Beuerle, F., & Feldmann, C. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.03.036 · Cited by 337
Luminescent rare-earth-based MOFs as optical sensors
Mahata, P., Mondal, S. K., Singha, D. K., & Majee, P. (2017) · Dalton Transactions · doi:10.1039/c6dt03419e · Cited by 292
Metadata
- Authors
- Zhou, X., Li, H., Xiao, H., Li, L., Zhao, Q., Yang, T., Zuo, J., & Huang, W.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 42
- Issue
- 16
- Pages
- 5718
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2004062271
- Cited by
- 228
- References
- 1
- FWCI
- 16.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, X., Li, H., Xiao, H., Li, L., Zhao, Q., Yang, T., Zuo, J., & Huang, W. (2013). A microporous luminescent europium metal–organic framework for nitro explosive sensing. Dalton Transactions. https://doi.org/10.1039/c3dt00055a
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