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Amine functionalized K10 montmorillonite: a solid acid–base catalyst for the Knoevenagel condensation reaction
Abstract
Different amine functionalized K10 montmorillonites were hydrothermally fabricated by a simple method of treatment of the neat clay with different amine solutions and used as heterogeneous catalysts towards the Knoevenagel condensation reaction. Catalytic results show that the di-amine functionalized K10 montmorillonite exhibits high efficacy for promoting this reaction at room temperature and in the absence of a solvent. The solid catalyst was characterized using a variety of different techniques; including Fourier transform infrared spectroscopy (FT-IR), nitrogen physisorption measurements, (29)Si CP MAS NMR spectroscopy, NH3-temperature programmed desorption (NH3-TPD), X-ray powder diffraction (XRD), and field emission scanning electron microscopy (FESEM). The catalyst could be recycled and reused for several runs without any loss of inherent catalytic activity.
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Metadata
- Authors
- Varadwaj, G. B. B., Rana, S., & Parida, K. M.
- Affiliations
- Institute of Minerals and Materials Technology (IN)
- Corresponding author
- Parida, K. M.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 42
- Issue
- 14
- Pages
- 5122
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W1979563897
- Cited by
- 105
- References
- 24
- Citations by year
- 2026: 1 · 2025: 5 · 2024: 6 · 2023: 11 · 2022: 4 · 2021: 10 · 2020: 7 · 2019: 7 · 2018: 9 · 2017: 17 · 2016: 8 · 2015: 5 · 2014: 9 · 2013: 6
- FWCI
- 3.56
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Dalton Transactions (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Clay minerals and soil interactions
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Keywords
- montmorillonite K10, amine functionalization, Knoevenagel condensation, hydrothermal treatment, solvent-free synthesis, catalyst reusability, clay modification
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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