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p–n Heterojunction photoelectrodes composed of Cu2O-loaded TiO2 nanotube arrays with enhanced photoelectrochemical and photoelectrocatalytic activities

Wang, Mengye, Sun, Lan, Lin, Zhiqun, Cai, Jianhuai, Xie, Kunpeng, Lin, Changjian·2013·Energy & Environmental Science

Abstract

Cu2O/TiO2 p–n heterojunction photoelectrodes were prepared by depositing different amounts of p-type Cu2O nanoparticles on n-type TiO2 nanotube arrays (i.e., forming Cu2O/TiO2 composite nanotubes) via an ultrasonication-assisted sequential chemical bath deposition. The success of deposition of Cu2O nanoparticles was corroborated by structural and composition characterizations. The enhanced absorption in the visible light region was observed in Cu2O/TiO2 composite nanotubes. The largely improved separation of photogenerated electrons and holes was revealed by photocurrent measurements. Consequently, Cu2O/TiO2 heterojunction photoelectrodes exhibited a more effective photoconversion capability than TiO2 nanotubes alone in photoelectrochemical measurements. Furthermore, Cu2O/TiO2 composite photoelectrodes also possessed superior photoelectrocatalytic activity and stability in the degradation of Rhodamine B. Intriguingly, by selecting an appropriate bias potential, a synergistic effect between electricity and visible light irradiation can be achieved.

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Metadata

Authors
Wang, M., Sun, L., Lin, Z., Cai, J., Xie, K., & Lin, C.
Venue
Energy & Environmental Science
Published
2013
Volume
6
Issue
4
Pages
1211
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
OpenAlex
W2133467767
Cited by
524
References
1
FWCI
23.68
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: p–n Heterojunction photoelectrodes composed of Cu2O-loaded TiO2 nanotube arrays with enhanced photoelectrochemical and photoelectrocatalytic activities. https://app.cochat.ai/papers/10.1039/c3ee24162a
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Wang, M., Sun, L., Lin, Z., Cai, J., Xie, K., & Lin, C. (2013). p–n Heterojunction photoelectrodes composed of Cu2O-loaded TiO2 nanotube arrays with enhanced photoelectrochemical and photoelectrocatalytic activities. Energy & Environmental Science. https://doi.org/10.1039/c3ee24162a

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