The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Copper-based catalysts for the efficient conversion of carbohydrate biomass into γ-valerolactone in the absence of externally added hydrogen
Abstract
The direct production of γ-valerolactone (GVL), an essential component for next-generation biorefineries, by a straightforward conversion of bio-derived levulinic acid (LA)/formic acid (FA) streams without the externally added fossil-fuel H2 has rarely been achieved. We describe here a sustainable, cost-effective and highly efficient protocol for directly converting a 1 : 1 aqueous mixture of LA and FA into GVL in high yields. The process is catalyzed by an earth-abundant and robust copper-based metal oxide catalyst, in which the high performance of the copper catalyst for the in situ generation of hydrogen gas in the systems by the highly selective decomposition of FA in an aqueous medium is essential. This catalytic system is also effective with raw cellulosic biomass, such as giant reed, as the starting material, thus paving a new way toward a renewable chemical industry.
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Citations
Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Cited by
Dutta, S., Yu, I. K. M., Tsang, D. C. W., Ng, Y. H., Ok, Y. S., Sherwood, J., & Clark, J. H. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.04.199 · Cited by 425
Nie, R., Tao, Y., Nie, Y., Lu, T., Wang, J., Zhang, Y., Lu, X., & Xu, C. C. (2021) · ACS Catalysis · doi:10.1021/acscatal.0c04939 · Cited by 341
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
Li, H., Fang, Z., Smith, R. L., & Yang, S. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2016.04.004 · Cited by 284
Metadata
- Authors
- Yuan, J., Li, S.-S., Yu, L., Liu, Y.-M., Cao, Y., He, H.-Y., & Fan, K.-N.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 6
- Issue
- 11
- Pages
- 3308
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2128900118
- Cited by
- 184
- References
- 1
- FWCI
- 9.21
- Type
- journal article
- Language
- en
- Open access
- closed
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