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N-doped graphene film-confined nickel nanoparticles as a highly efficient three-dimensional oxygen evolution electrocatalyst
Abstract
A three-dimensional (3D) catalyst was fabricated by using N-doped graphene films as scaffolds and nickel nanoparticles as building blocks via a heterogeneous reaction process. This unique structure enables high catalyst loadings and optimal electrode contact, leading to a surprisingly high catalytic activity towards OER, which almost approaches that of the state-of-the-art precious OER electrocatalysts (IrO2). Moreover, the catalytic process features favourable electrode kinetics and strong durability during long-term cycling. The dual-active-site mechanism was proposed for this 3D catalyst, i.e., Ni/NiOOH and Ni–N(O)–C are both active sites. The enhanced performance is attributed to synergistic effects of N-doped graphene and Ni, which enhance the activities of both components for OER.
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Cites
Wang, H., Maiyalagan, T., & Wang, X. (2012) · ACS Catalysis · doi:10.1021/cs200652y · Cited by 3,618
Graphene Hydrogels Deposited in Nickel Foams for High‐Rate Electrochemical Capacitors
Chen, J., Sheng, K., Luo, P., Li, C., & Shi, G. (2012) · Advanced Materials · doi:10.1002/adma.201201978 · Cited by 438
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Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Recent developments in emerging two-dimensional materials and their applications
Khan, K., Tareen, A. K., Aslam, M., Wang, R., Zhang, Y., Mahmood, A., Ouyang, Z., Zhang, H., & Guo, Z. (2020) · Journal of Materials Chemistry C · doi:10.1039/c9tc04187g · Cited by 886
Advanced Architectures and Relatives of Air Electrodes in Zn–Air Batteries
Pan, J., Xu, Y. Y., Yang, H., Dong, Z., Liu, H., & Xia, B. Y. (2018) · Advanced Science · doi:10.1002/advs.201700691 · Cited by 848
Hou, Y., Lohe, M. R., Zhang, J., Liu, S., Zhuang, X., & Feng, X. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03440j · Cited by 824
Metadata
- Authors
- Chen, S., Duan, J., Ran, J., Jaroniec, M., & Qiao, S. Z.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 6
- Issue
- 12
- Pages
- 3693
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2032516721
- Cited by
- 334
- References
- 2
- FWCI
- 12.26
- Type
- journal article
- Language
- en
- Open access
- closed
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