The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation
Abstract
The incentive for use of renewable resources to replace fossil sources is motivating extensive research on new and alternative fuels derived from biomass. Bio-oils derived from cellulosic biomass offer the prospect of becoming a major feedstock for production of fuels and chemicals, and lignin is a plentiful, underutilized component of cellulosic biomass. Lignin conversion requires depolymerization and removal of oxygen. Likely processes for lignin conversion involve depolymerization (e.g., by pyrolysis) and catalytic upgrading of the resultant bio-oils. A major goal of the upgrading is catalytic hydrodeoxygenation (HDO), which involves reactions with hydrogen that produce hydrocarbons and water. The aim of this review is to present a critical introduction to HDO chemistry focused on compounds derived from lignin, including a summary of HDO reactions and those that accompany them, with a comparison of catalysts addressing their activities, selectivities, and stabilities. The reactions are evaluated in terms of reaction pathways of compounds representative of lignin-derived bio-oils, including anisole, guaiacol, and phenol. The review includes recommendations for further research and an attempt to place HDO in a context of options for renewable fuels and chemicals, but it does not provide an economic assessment.
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Cites
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
Mohan, D., Pittman, C. U., & Steele, P. H. (2006) · Energy & Fuels · doi:10.1021/ef0502397 · Cited by 5,663
Review of fast pyrolysis of biomass and product upgrading
Bridgwater, A. V. (2012) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2011.01.048 · Cited by 4,856
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
Zakzeski, J., Bruijnincx, P. C. A., Jongerius, A. L., & Weckhuysen, B. M. (2010) · Chemical Reviews · doi:10.1021/cr900354u · Cited by 4,468
Catalytic conversion of biomass to biofuels
Alonso, D. M., Bond, J. Q., & Dumesic, J. A. (2010) · Green Chemistry · doi:10.1039/c004654j · Cited by 2,333
Competitive liquid biofuels from biomass
Demirbas, A. (2011) · Applied Energy · doi:10.1016/j.apenergy.2010.07.016 · Cited by 796
Fast Pyrolysis Bio-Oils from Wood and Agricultural Residues
Oasmaa, A., Solantausta, Y., Arpiainen, V., Kuoppala, E., & Sipilä, K. (2010) · Energy & Fuels · doi:10.1021/ef901107f · Cited by 407
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Hu, L., Lin, L., Wu, Z., Zhou, S., & Liu, S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.042 · Cited by 445
De, S., Saha, B., & Luque, R. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2014.09.065 · Cited by 359
Zhang, H., Xiao, R., Nie, J., Jin, B., Shao, S., & Xiao, G. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.05.040 · Cited by 158
Wang, C., Zhang, X., Liu, Q., Zhang, Q., Chen, L., & Ma, L. (2020) · Fuel Processing Technology · doi:10.1016/j.fuproc.2020.106485 · Cited by 157
Metadata
- Authors
- Saidi, M., Samimi, F., Karimipourfard, D., Nimmanwudipong, T., Gates, B. C., & Rahimpour, M. R.
- Venue
- Energy Environ. Sci.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 7
- Issue
- 1
- Pages
- 103-129
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W1967242782
- Cited by
- 944
- References
- 6
- FWCI
- 28.70
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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