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LDH nanocages synthesized with MOF templates and their high performance as supercapacitors
Abstract
Layered double hydroxides (LDHs) are currently attracting intense research interest for their various applications. Three LDH hollow nano-polyhedra are synthesized with zeolitic imidazolate framework-67 (ZIF-67) nanocrystals as the templates. The nanocages well inherit the rhombic dodecahedral shape of the ZIF-67 templates, and the shell is composed of nanosheets assembled with an edge-to-face stacking. This is the first synthesis of the LDH non-spherical structures. And the mechanism of utilizing metal-organic framework (MOF) nanocrystals as templates is explored. Control of the simultaneous reactions, the precipitation of the shells and the template etching, is extremely crucial to the preparation of the perfect nanocages. And the Ni-Co LDH nanocages exhibit superior pseudocapacitance property due to their novel hierarchical and submicroscopic structures.
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Cited by
Wang, T., Zhang, S., Yan, X., Lyu, M., Wang, L., Bell, J., & Wang, H. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02987 · Cited by 459
Li, X., Gao, X., Ai, L., & Jiang, J. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.03.127 · Cited by 382
Ming, F., Liang, H., Shi, H., Xu, X., Mei, G., & Wang, Z. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta06496e · Cited by 332
Ni-Doped Cobalt–Cobalt Nitride Heterostructure Arrays for High-Power Supercapacitors
Liu, X., Zang, W., Guan, C., Zhang, L., Qian, Y., Elshahawy, A. M., Zhao, D., Pennycook, S. J., & Wang, J. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01393 · Cited by 253
Song, W., Teng, X., Liu, Y., Wang, J., Niu, Y., He, X., Zhang, C., & Chen, Z. (2019) · Nanoscale · doi:10.1039/c9nr00411d · Cited by 148
Metadata
- Authors
- Jiang, Z., Li, Z., Qin, Z., Sun, H., Jiao, X., & Chen, D.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 5
- Issue
- 23
- Pages
- 11770
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2163838061
- Cited by
- 665
- References
- 0
- FWCI
- 7.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jiang, Z., Li, Z., Qin, Z., Sun, H., Jiao, X., & Chen, D. (2013). LDH nanocages synthesized with MOF templates and their high performance as supercapacitors. Nanoscale. https://doi.org/10.1039/c3nr03829g
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