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Photocatalysts with internal electric fields

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Li, Li, Salvador, Paul A., Rohrer, Gregory S.·2014·Nanoscale
DOI 10.1039/c3nr03998f
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Abstract

The photocatalytic activity of materials for water splitting is limited by the recombination of photogenerated electron-hole pairs as well as the back-reaction of intermediate species. This review concentrates on the use of electric fields within catalyst particles to mitigate the effects of recombination and back-reaction and to increase photochemical reactivity. Internal electric fields in photocatalysts can arise from ferroelectric phenomena, p-n junctions, polar surface terminations, and polymorph junctions. The manipulation of internal fields through the creation of charged interfaces in hierarchically structured materials is a promising strategy for the design of improved photocatalysts.

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Metadata

Authors
Li, L., Salvador, P. A., & Rohrer, G. S.
Venue
Nanoscale
Publisher
Royal Society of Chemistry (RSC)
Published
2014
Volume
6
Issue
1
Pages
24-42
ISSN
  • 2040-3364 (ISSN-L)
  • 2040-3372
DOI
10.1039/c3nr03998f
OpenAlex
W2138007064
Cited by
774
References
174
FWCI
16.47
Type
journal article
Language
en
Open access
hybrid

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Li, L., Salvador, P. A., & Rohrer, G. S. (2014). Photocatalysts with internal electric fields. Nanoscale. https://doi.org/10.1039/c3nr03998f

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