The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Sunlight induced atom transfer radical polymerization by using dimanganese decacarbonyl
Abstract
A new photoredox catalyst system for atom transfer radical polymerization is developed on the basis of visible light photocatalysis using dimanganese decacarbonyl (Mn2(CO)10) that initiates and controls the polymerization at ambient temperature. The polymerization was performed by a Mn2(CO)10–alkyl halide system with visible- or sunlight in the presence of parts per million (ppm) copper catalysts. The photogenerated ˙Mn(CO)5 radicals are not only able to abstract halogen atoms from alkyl halides to generate carbon centered radicals but also reduce the CuIIBr2 to CuIBr directly, which was used as an activator in the Atom Transfer Radical Polymerization (ATRP) of vinyl monomers such as methyl methacrylate, methyl acrylate and styrene. The method was also used to synthesize graft copolymers from commercially available poly(vinyl chloride) without additional modification.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Progress in Controlled Radical Polymerization: Mechanisms and Techniques
(2012) · ACS Symposium Series · doi:10.1021/bk-2012-1100 · Cited by 87
Cited by
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
Xu, J., Jung, K., Atme, A., Shanmugam, S., & Boyer, C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501745g · Cited by 990
Photoinduced Electron Transfer Reactions for Macromolecular Syntheses
Dadashi-Silab, S., Doran, S., & Yagci, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00586 · Cited by 846
Self-citationXu, J., Shanmugam, S., Duong, H. T., & Boyer, C. (2015) · Polymer Chemistry · doi:10.1039/c4py01317d · Cited by 446
Shanmugam, S., Xu, J., & Boyer, C. (2015) · Chemical Science · doi:10.1039/c4sc03342f · Cited by 255
Metadata
- Authors
- Ciftci, M., Tasdelen, M. A., & Yagci, Y.
- Venue
- Polym. Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 5
- Issue
- 2
- Pages
- 600-606
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W2151138497
- Cited by
- 168
- References
- 2
- FWCI
- 10.85
- Type
- journal article
- Language
- en
- Open access
- closed
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