The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Ring-opening metathesis polymerization of 8-membered cyclic olefins
Abstract
Ring-opening metathesis polymerization (ROMP) involving 8-membered cyclic olefins, such as the parent molecules cis-cyclooctene (COE) and cis,cis-1,5-cyclooctadiene (COD), leads to various polyalkenamers that have broad potential in a variety of fields. The use of different catalysts and diverse functionalized monomers allows for control over molar mass and architecture in the resultant polymers. We review the ROMP of unsubstituted and substituted COE and COD to tune the properties of the resultant homopolymers and copolymers. Starting with a survey of homopolymers, we report the strengths and limitations of the ROMP of functionalized 8-membered ring olefins. Then we show how these monomers are used to control crystallinity, hydrophobicity and morphology, in various types of copolymers.
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Citations
Cites
Chemically Cross-Linked Polycyclooctene: Synthesis, Characterization, and Shape Memory Behavior
Liu, C., Chun, S. B., Mather, P. T., Zheng, L., Haley, E. H., & Coughlin, E. B. (2002) · Macromolecules · doi:10.1021/ma021141j · Cited by 282
Cited by
Neal, J. A., Mozhdehi, D., & Guan, Z. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01601 · Cited by 465
Parke, S. M., Lopez, J. C., Cui, S., LaPointe, A. M., & Coates, G. W. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202301927 · Cited by 88
Synthesis of telechelic polyolefins
Yan, T., & Guironnet, D. (2021) · Polymer Chemistry · doi:10.1039/d1py00819f · Cited by 43
Metadata
- Authors
- Martinez, H., Ren, N., Matta, M. E., & Hillmyer, M. A.
- Venue
- Polymer Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 5
- Issue
- 11
- Pages
- 3507
- ISSN
- 1759-9954 (ISSN-L)
- 1759-9962
- OpenAlex
- W1982040855
- Cited by
- 178
- References
- 1
- FWCI
- 5.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- Martinez, H., Ren, N., Matta, M. E., & Hillmyer, M. A. (2014). Ring-opening metathesis polymerization of 8-membered cyclic olefins. Polymer Chemistry. https://doi.org/10.1039/c3py01787g
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