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Tubular graphitic-C3N4: a prospective material for energy storage and green photocatalysis
Open accessAbstract
We have established a facile and scaleable approach to fabricate tubular graphitic-C3N4 using melamine. The construction of the unique tubular morphology is a result of the pre-treatment of melamine with HNO3. Herein, for the first time, we have explored the electrochemical properties of g-C3N4 as an electrode material for supercapacitors. Tubular g-C3N4 has significant advantages due to its distinctive morphology, high surface area (182.61 m2 g−1) and combination of carbon with nitrogen. Therefore, tubular g-C3N4 demonstrated a good specific capacitance of 233 F g−1 at a current density of 0.2 A g−1 in 6 M KOH electrolyte. Furthermore, tubular g-C3N4 maintained a high capacitance retention capability (90%) after 1000 cycles. The photocatalytic activity of tubular g-C3N4 was evaluated using the organic dyes such as Methylene Blue (MB) and Methylene Orange (MO) under visible light. Tubular g-C3N4 demonstrated good photocatalytic activity and enhanced stability compared to bulk g-C3N4. The enhanced performance is because of the high surface area, which contains more active sites for reaction. The encouraging performance of tubular g-C3N4 in supercapacitors and as a photocatalyst points toward it being a prospective material for energy storage that is environmentally clean.
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Wei, J., Zhou, D., Sun, Z., Deng, Y., Xia, Y., & Zhao, D. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201202764 · Cited by 931
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Wen, P., Gong, P., Sun, J., Wang, J., & Yang, S. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02461g · Cited by 586
Wang, X., Hong, M., Zhang, F., Zhuang, Z., & Yu, Y. (2016) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.6b01024 · Cited by 258
Metadata
- Authors
- Tahir, M., Cao, C., Butt, F. K., Idrees, F., Mahmood, N., Ali, Z., Aslam, I., Tanveer, M., Rizwan, M., & Mahmood, T.
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 1
- Issue
- 44
- Pages
- 13949
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2047666782
- Cited by
- 269
- References
- 1
- FWCI
- 7.42
- Type
- journal article
- Language
- en
- Open access
- green
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- Tahir, M., Cao, C., Butt, F. K., Idrees, F., Mahmood, N., Ali, Z., Aslam, I., Tanveer, M., Rizwan, M., & Mahmood, T. (2013). Tubular graphitic-C3N4: a prospective material for energy storage and green photocatalysis. Journal of Materials Chemistry A. https://doi.org/10.1039/c3ta13291a
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