Two-way shape memory polymer with “switch–spring” composition by interpenetrating polymer network
Abstract
In the present work, a novel molecular strategy was employed to fabricate a two-way shape memory polymer (2WSMP), which is an interpenetrating network (IPN) with elastomeric and crystalline components leading to a “switch–spring” composition. In this 2WSMP the switch, a PCL crystalline network, is responsible for the reversible shape shrinkage. While the spring, the compressed PTMEG elastomeric network, provides the push force for shape expansion. This IPN polymer has the desired two-way shape effect (2WSME) as proved by DMA.
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The two-stage cross-linking method has been used to fabricate stress-free two-way SMPs.
“The two-stage cross-linking method has been used to fabricate stress-free two-way SMPs, i.e., class (ii); e.g., in [136-138].”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [136]
By reheating the sample, PCL melted opening the switch and PTMEG underwent a compression movement.
“Afterwards, by reheating the sample, PCL melted ''opening of the switch' and the PTMEG undergone a compression movement.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [93]
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References 32 · Cited by 144
- Authors
- Wu, Y., Hu, J., Han, J., Zhu, Y., Huang, H., Li, J., & Tang, B.
- Affiliations
- Hong Kong Polytechnic University (HK)
- Hong Kong University of Science and Technology (HK)
- Corresponding author
- Hu, J.
- Venue
- J. Mater. Chem. A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014-09-05
- Volume
- 2
- Issue
- 44
- Pages
- 18816-18822
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W1973485226
- Cited by
- 144
- References
- 32
- Citations by year
- 2026: 7 · 2025: 17 · 2024: 7 · 2023: 9 · 2022: 21 · 2021: 17 · 2020: 16 · 2019: 13 · 2018: 14 · 2017: 9 · 2016: 8 · 2015: 4 · 2014: 2
- FWCI
- 8.92
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- Rare & Special e-Zone (The Hong Kong University of Science and Technology) (submittedVersion)
- PolyU Institutional Research Archive (Hong Kong Polytechnic University) (submittedVersion)
- Funders
- Research Grants Council, University Grants Committee, Hong Kong (PolyU 5162/12E)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- interpenetrating polymer networks, polycaprolactone, crystalline network, elastomeric networks
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