Cited by 144Advanced Materials and MechanicsPolymer composites and self-healingPolymer crystallization and properties

Two-way shape memory polymer with “switch–spring” composition by interpenetrating polymer network

Wu, Y., Hu, J., Han, J., Zhu, Y., Huang, H., Li, J., Tang, B.·2014·J. Mater. Chem. A

Abstract

In the present work, a novel molecular strategy was employed to fabricate a two-way shape memory polymer (2WSMP), which is an interpenetrating network (IPN) with elastomeric and crystalline components leading to a “switch–spring” composition. In this 2WSMP the switch, a PCL crystalline network, is responsible for the reversible shape shrinkage. While the spring, the compressed PTMEG elastomeric network, provides the push force for shape expansion. This IPN polymer has the desired two-way shape effect (2WSME) as proved by DMA.

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Crossref · 10.1039/c4ta03640a

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  • The two-stage cross-linking method has been used to fabricate stress-free two-way SMPs.

    “The two-stage cross-linking method has been used to fabricate stress-free two-way SMPs, i.e., class (ii); e.g., in [136-138].”
  • By reheating the sample, PCL melted opening the switch and PTMEG underwent a compression movement.

    “Afterwards, by reheating the sample, PCL melted ''opening of the switch' and the PTMEG undergone a compression movement.”

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References 32 · Cited by 144

Authors
Wu, Y., Hu, J., Han, J., Zhu, Y., Huang, H., Li, J., & Tang, B.
Affiliations
  • Hong Kong Polytechnic University (HK)
  • Hong Kong University of Science and Technology (HK)
Corresponding author
Hu, J.
Venue
J. Mater. Chem. A
Published
2014-09-05
Volume
2
Issue
44
Pages
18816-18822
ISSN
  • 2050-7488 (ISSN-L)
  • 2050-7496
OpenAlex
W1973485226
Cited by
144
References
32
Citations by year
2026: 7 · 2025: 17 · 2024: 7 · 2023: 9 · 2022: 21 · 2021: 17 · 2020: 16 · 2019: 13 · 2018: 14 · 2017: 9 · 2016: 8 · 2015: 4 · 2014: 2
FWCI
8.92
Type
journal article
Language
en
Open access
closed
Locations
  • Journal of Materials Chemistry A (publishedVersion)
  • Rare & Special e-Zone (The Hong Kong University of Science and Technology) (submittedVersion)
  • PolyU Institutional Research Archive (Hong Kong Polytechnic University) (submittedVersion)
Funders
Research Grants Council, University Grants Committee, Hong Kong (PolyU 5162/12E)
Topics
  • Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Keywords
interpenetrating polymer networks, polycaprolactone, crystalline network, elastomeric networks

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