The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Tuning of fluorine content in graphene: towards large-scale production of stoichiometric fluorographene
Open accessAbstract
The availability of well-defined modified graphene derivatives such as fluorographene, graphane, thiographene or hydroxygraphene is of pivotal importance for tuning the resulting material properties in numerous potential applications. A series of fluorinated graphene with various contents of fluorine was synthesized by a simple fluorination procedure in an autoclave with a nitrogen/fluorine atmosphere at different exposure times and temperatures. To investigate the composition, structure and properties all samples were characterized in detail by a number of analytical techniques such as SEM, XRD, EDS, AFM, STEM, combustible elemental analysis, STA, XPS, Raman spectroscopy, UV-VIS spectroscopy and cyclic voltammetry. The fully fluorinated graphene with the overall stoichiometry C1F1.05 had a bright white color indicating a significant change of band-gap. In comparison to other samples such a high concentration of fluorine led to the occurrence of exotic thermal behavior, strong luminescence in the visible spectral region and also the unique super-hydrophobic behavior observed on the material surface. The described tunable fluorination should pave the way to fluorographene based devices with tailored properties.
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Cites
Graphene-based nanomaterials and their electrochemistry
Pumera, M. (2010) · Chemical Society Reviews · doi:10.1039/c002690p · Cited by 1,117
Cited by
Two‐Dimensional Fluorinated Graphene: Synthesis, Structures, Properties and Applications
Feng, W., Long, P., Feng, Y., & Li, Y. (2016) · Advanced Science · doi:10.1002/advs.201500413 · Cited by 640
Chemistry, properties, and applications of fluorographene
Chronopoulos, D. D., Bakandritsos, A., Pykal, M., Zbořil, R., & Otyepka, M. (2017) · Applied Materials Today · doi:10.1016/j.apmt.2017.05.004 · Cited by 284
Metadata
- Authors
- Mazánek, V., Jankovský, O., Luxa, J., Sedmidubský, D., Janoušek, Z., Šembera, F., Mikulics, M., & Sofer, Z.
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2015
- Volume
- 7
- Issue
- 32
- Pages
- 13646-13655
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W1849299596
- Cited by
- 180
- References
- 1
- FWCI
- 7.99
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Mazánek, V., Jankovský, O., Luxa, J., Sedmidubský, D., Janoušek, Z., Šembera, F., Mikulics, M., & Sofer, Z. (2015). Tuning of fluorine content in graphene: towards large-scale production of stoichiometric fluorographene. Nanoscale. https://doi.org/10.1039/c5nr03243a
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