Metal–organic framework-based CoP/reduced graphene oxide: high-performance bifunctional electrocatalyst for overall water splitting
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A Co-based MOF/GO sandwich-type composite with a sheet-like shape was fabricated, and converted to porous CoP/rGO with a retained layered structure. CoP/rGO exhibits superb HER activity in acid solution, and can also be used as a bifunctional catalyst for water splitting in basic media.
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The C-P peak at 285.2 eV confirms that P atoms are doped in carbon.
“the C–P peak is observed at 285.2 eV, further confirming that P atoms are doped in carbon.43,44”
From M <sub>X</sub> P(M = Co/Ni)@carbon core–shell nanoparticles embedded in 3D cross-linked graphene aerogel derived from seaweed biomass for hydrogen evolution reaction (2018) · cites this paper as [43]
The Results and discussion section reports XPS peaks for cobalt phosphide and phosphate, but does not identify a C–P peak at 285.2 eV or say that phosphorus is doped into carbon. Searches for the binding energy, C–P bonding, and phosphorus doping did not locate support in our copy; the passages have no page numbers. (LLM, conf=0.76)
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References 58 · Cited by 798
Research works printed but not linked: 3
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- Authors
- Jiao, L., Zhou, Y.-X., & Jiang, H.-L.
- Affiliations
- University of Science and Technology of China (CN)
- Hefei National Laboratory for Physical Sciences at the Microscale
- Corresponding author
- Jiang, Hai-Long
- Venue
- Chemical Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 7
- Issue
- 3
- Pages
- 1690-1695
- ISSN
- 2041-6520 (ISSN-L)
- 2041-6539
- PMC
- PMC5964964
- OpenAlex
- W2238462834
- Cited by
- 798
- References
- 58
- Citations by year
- 2026: 24 · 2025: 34 · 2024: 47 · 2023: 54 · 2022: 67 · 2021: 87 · 2020: 101 · 2019: 113 · 2018: 127 · 2017: 109 · 2016: 35
- FWCI
- 34.75
- Type
- journal article
- Language
- en
- Open access
- diamond
- doi.org
- Licence
- cc-by-nc
- Locations
- Chemical Science (publishedVersion, cc-by-nc)
- Europe PMC (PubMed Central) (publishedVersion, cc-by-nc)
- PubMed Central (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21371162, 51301159, 21521001)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Keywords
- metal-organic frameworks, cobalt phosphide, reduced graphene oxide, bifunctional electrocatalysts, overall water splitting, hydrogen evolution reaction, oxygen evolution reaction
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