Chirality in adsorption on solid surfaces
Abstract
Chemical chirality on solid surfaces has important implications in analytical separations, selective crystallizations and catalysis, and may help explain the origin of homochirality in life.
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The three-point model fails to fully explain chiral recognition.
“But this model, assuming that only one enantiomer can present three groups that match three active positions of the chiral surface, 243 fails to fully explain chiral recognition which are the fruit of more subtle interactions.244”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [244]
Chiral metal surfaces display high adsorption enantioselectivities.
“The last two decades have seen the emergence of chiral metal surfaces displaying high adsorption enantioselectivities. 239,244,296”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [244]
Cites
Asymmetric autocatalysis and amplification of enantiomeric excess of a chiral molecule
Soai, K., Shibata, T., Morioka, H., & Choji, K. (1995) · Nature · doi:10.1038/378767a0 · Cited by 1,085 · see citing works
Nonlinear Effects in Asymmetric Catalysis
Satyanarayana, T., Abraham, S., & Kagan, H. B. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200705241 · Cited by 591 · see citing works
Chiral selection on inorganic crystalline surfaces
Hazen, R. M., & Sholl, D. S. (2003) · Nature Materials · doi:10.1038/nmat879 · Cited by 488 · see citing works
Michaeli, K., Kantor-Uriel, N., Naaman, R., & Waldeck, D. H. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00369a · Cited by 291 · see citing works
Crystalline Architectures as Templates of Relevance to the Origins of Homochirality
Weissbuch, I., & Lahav, M. (2011) · Chemical Reviews · doi:10.1021/cr1002479 · Cited by 284 · see citing works
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Possible chemical and physical scenarios towards biological homochirality
Sallembien, Q., Bouteiller, L., Crassous, J., & Raynal, M. (2022) · Chemical Society Reviews · doi:10.1039/d1cs01179k · Cited by 186 · see citing works
- Authors
- Zaera, F.
- Affiliations
- University of California, Riverside (US)
- Corresponding author
- Zaera, Francisco
- ORCID
- Zaera, Francisco
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2017
- Volume
- 46
- Issue
- 23
- Pages
- 7374-7398
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2766402337
- Cited by
- 172
- References
- 5
- Citations by year
- 2026: 16 · 2025: 18 · 2024: 23 · 2023: 18 · 2022: 16 · 2021: 23 · 2020: 28 · 2019: 15 · 2018: 11 · 2017: 4
- FWCI
- 1.27
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Society Reviews (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Basic Energy Sciences (DE-SC0008703)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Surface Chemistry and Catalysis
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Keywords
- surface chirality, chiral adsorption, enantiomers, enantiomeric mixtures, prochiral molecules, enantioselectivity, surface reconstruction, enantioselective crystallization, chiral chromatography, asymmetric catalysis, metal single crystals, pyrolytic graphite
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