A facile and surfactant-free route for nanomanufacturing of tailored ternary nanoalloys as superior oxygen reduction reaction electrocatalysts
Abstract
Laser ablation synthesis in solution-galvanic replacement reaction (LASiS-GRR) enables tuning of elemental ratios and bonding properties for Pt based ternary nanoalloys as ORR electrocatalysts.
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PtCuCo ternary alloy showed the best ORR activity owing to incorporation of Cu shifting the Pt d-band to an optimal position between Pt and PtCo binary alloys, tuning binding affinities for oxygen and oxygenated species.
“Thus, the fabricated ternary alloy showed the best ORR activity owing to the incorporation of Cu, shift back the Pt d-band in the optimal position between Pt and PtCo binary alloys, hence tuning the binding affinities for oxygen and oxygenated species.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [232]
Cites
Wang, D., Xin, H. L., Hovden, R., Wang, H., Yu, Y., Muller, D. A., DiSalvo, F. J., & Abruña, H. D. (2013) · Nature Materials · doi:10.1038/nmat3458 · Cited by 2,082 · see citing works
Shao, M., Peles, A., & Shoemaker, K. (2011) · Nano Letters · doi:10.1021/nl2017459 · Cited by 878 · see citing works
Mani, P., Srivastava, R., & Strasser, P. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.07.047 · Cited by 379 · see citing works
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Theerthagiri, J., Karuppasamy, K., Lee, S. J., Shwetharani, R., Kim, H.-S., Pasha, S. K. K., Ashokkumar, M., & Choi, M. Y. (2022) · Light: Science & Applications · doi:10.1038/s41377-022-00904-7 · Cited by 461 · see citing works
Ribeiro, E. L., Davis, E. M., Mokhtarnejad, M., Hu, S., Mukherjee, D., & Khomami, B. (2021) · Catalysis Science & Technology · doi:10.1039/d0cy02099k · Cited by 34 · see citing works
Self-citation
- Authors
- Hu, S., Cheng, K., Ribeiro, E. L., Park, K., Khomami, B., & Mukherjee, D.
- Affiliations
- University of Tennessee at Knoxville (US)
- Corresponding author
- Khomami, Bamin
- Mukherjee, Dibyendu
- Venue
- Catalysis Science & Technology
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2017
- Volume
- 7
- Issue
- 10
- Pages
- 2074-2086
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2604599725
- Cited by
- 55
- References
- 3
- Citations by year
- 2026: 3 · 2025: 1 · 2024: 4 · 2023: 5 · 2022: 3 · 2021: 9 · 2020: 11 · 2019: 12 · 2018: 4 · 2017: 3
- FWCI
- 2.20
- Type
- journal article
- Language
- en
- Update notices
- correction (2017-06-30)
- Open access
- closed
- Locations
- Catalysis Science & Technology (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Materials Science › Materials Chemistry › Advanced Nanomaterials in Catalysis
- Keywords
- oxygen reduction reaction, electrocatalysts, laser ablation synthesis, surfactant-free synthesis, bonding properties
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