The role of ligand redox non-innocence in ring-opening polymerization reactions catalysed by bis(imino)pyridine iron alkoxide complexes
Abstract
The reactivity of iron-based ring opening polymerization catalysts is compared when the catalyst is in three different oxidation states.
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Comparatively little research has been directed at using inexpensive iron catalysts for effective ROP reactions.
“Still, comparatively little research has been directed at using inexpensive iron catalysts for effective ROP reactions.”
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References 66 · Cited by 48
- Authors
- Delle Chiaie, K. R., Biernesser, A. B., Ortuño, M. A., Dereli, B., Iovan, D. A., Wilding, M. J. T., Li, B., Cramer, C. J., & Byers, J. A.
- Affiliations
- Eugene F. Merkert Chemistry Center
- Boston College (US)
- Department of Chemistry
- University of Minnesota (US)
- Harvard University (US)
- Corresponding author
- Byers, J. A.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2017
- Volume
- 46
- Issue
- 38
- Pages
- 12971-12980
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2756160908
- Cited by
- 48
- References
- 66
- Citations by year
- 2024: 3 · 2023: 7 · 2022: 4 · 2021: 7 · 2020: 9 · 2019: 7 · 2018: 11
- FWCI
- 2.66
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Dalton Transactions (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Army Research Office (66672-CH W911NF-15-1-0454)
- Division of Chemistry (CHE-1361595)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- ring-opening polymerization, bis(imino)pyridine ligands, iron oxidation state, cyclic esters, cyclic carbonates, copolymerization, antiferromagnetic coupling, high-spin iron(II), electronic structure
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