Cited by 53Solid-state spectroscopy and crystallographyFerroelectric and Piezoelectric MaterialsCrystallography and molecular interactions

Strong polarization switching with low-energy loss in hydrogen-bonded organic antiferroelectrics

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Horiuchi, S., Kumai, R., Ishibashi, S.·2018·Chemical Science

Abstract

Highly efficient switching of strong polarization in squaric acid crystal arises from 90° rotation of sheet polarization in a pseudo-tetragonal lattice.

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Crossref · 10.1039/c7sc03859c

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  • The extracted critical fields Ef and Ea do not drop to zero at Tc, but instead reach a plateau above 200 °C, suggesting these extracted fields above Tc might not have a physical meaning.

    “However, they [Fig.3(d)] do not drop to zero at Tc, as it could have been expected from past examples of E-T phase diagrams 33 or phenomenological theory.34 Instead, both values of E f and Ea seem to reach a plateau above 200 ○ C, suggesting that these extracted fields above Tc might not have a physical meaning.”

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Cites

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Research works printed but not linked: 18

  1. Lines M. E. and Glass A. M., Principles and Applications of Ferroelectrics and Related Materials, Oxford University Press, New York, 1977.
  2. Horiuchi S. Tokura Y. Nat. Mater. 2008 7 357 18432209
  3. Tayi A. S. Kaeser A. Matsumoto M. Aida T. Stupp S. I. Nat. Chem. 2015 7 281 25803466
  4. Horiuchi S. Tokunaga Y. Giovannetti G. Picozzi S. Itoh H. Shimano R. Kumai R. Tokura Y. Nature 2010 463 789 20148035
  5. Horiuchi S. Kagawa F. Hatahara K. Kobayashi K. Kumai R. Murakami Y. Tokura Y. Nat. Commun. 2012 3 1308 23250438 PMC3535420
  6. Horiuchi S. Kobayashi K. Kumai R. Ishibashi S. Nat. Commun. 2017 8 14426 28205550 PMC5316872
  7. Owczarek M. Hujsak K. A. Ferris D. P. Prokofjevs A. Majerz I. Szklarz P. Zhang H. Sarjeant A. A. Stern C. L. Jakubas R. Hong S. Dravid V. P. Stoddart J. F. Nat. Commun. 2016 7 13108 27734829 PMC5065626
  8. Kobayashi K. Horiuchi S. Ishibashi S. Kagawa F. Murakami Y. Kumai R. Chem.–Eur. J. 2014 20 17515 25363720
  9. Rabe K. M., in Functional Metal Oxides: New Science and Novel Applications, ed. S. B. Ogale, T. V. Venkatesan and M. G. Blamire, Wiley-VCH, Weinheim, 2013, vol. 7, pp. 221–244.
  10. Park M. H. Lee Y. H. Kim H. J. Kim Y. J. Moon T. Kim K. D. Müller J. Kersch A. Schroeder U. Mikolajick T. Hwang C. S. Adv. Mater. 2015 27 1811 25677113
  11. Feder J., in Oxocarbons, ed. R. West, Academic Press, New York, 1980, vol. 8, pp. 141–167.
  12. Oxocarbons, ed. R. West, Academic Press, New York, 1980.
  13. Kumai R. Horiuchi S. Okimoto Y. Tokura Y. J. Chem. Phys. 2006 125 084715 16965047
  14. Moritomo Y. Tokura Y. Takahashi H. Mori N. Phys. Rev. Lett. 1991 67 2041 10044320
  15. Ahn C. W. Amarsanaa G. Won S. S. Chae S. A. Lee D. S. Kim I. W. ACS Appl. Mater. Interfaces 2015 7 26381 26606502
  16. King-Smith R. D. Vanderbilt D. Phys. Rev. B 1993 47 1651 10006189
  17. Blöchl P. E. Phys. Rev. B 1994 50 17953 9976227
  18. Perdew J. P. Burke K. Ernzerhof M. Phys. Rev. Lett. 1996 77 3865 10062328

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Authors
Horiuchi, S., Kumai, R., & Ishibashi, S.
Affiliations
  • National Institute of Advanced Industrial Science and Technology (JP)
  • High Energy Accelerator Research Organization (JP)
Corresponding author
Horiuchi, S.
Venue
Chemical Science
Published
2018
Volume
9
Issue
2
Pages
425-432
ISSN
  • 2041-6520 (ISSN-L)
  • 2041-6539
OpenAlex
W2766377641
Cited by
53
References
0
Citations by year
2026: 5 · 2025: 3 · 2024: 7 · 2023: 6 · 2022: 7 · 2021: 10 · 2020: 8 · 2019: 3 · 2018: 4
FWCI
1.73
Type
journal article
Language
en
Open access
Locations
  • Chemical Science (publishedVersion, cc-by)
  • Europe PMC (PubMed Central) (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
Funders
JSPS (JP16H02301)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
  • Physical Sciences › Materials Science › Materials Chemistry › Ferroelectric and Piezoelectric Materials
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Crystallography and molecular interactions
Keywords
polarization switching, squaric acid, low switching energy, ferroelectricity

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