Products and mechanism of the OH-initiated photo-oxidation of perfluoro ethyl vinyl ether, C 2 F 5 OCFCF 2
Open accessAbstract
The photo-oxidation of PEVE in 1 bar of air in the presence of NO x results in the formation of C 2 F 5 OCFO, FC(O)C(O)F and CF 2 O in molar yields of 0.50, 0.46 and 1.50, respectively.
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References 36 · Cited by 7
- Authors
- Bunkan, A. J. C., Srinivasulu, G., Amedro, D., Vereecken, L., Wallington, T. J., & Crowley, J. N.
- Affiliations
- Max Planck Institute for Chemistry (DE)
- Division of Atmospheric Chemistry
- Forschungszentrum Jülich (DE)
- Ford Motor Company (United States) (US)
- Corresponding author
- Crowley, J. N.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2018
- Volume
- 20
- Issue
- 16
- Pages
- 11306-11316
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2797368032
- Cited by
- 7
- References
- 36
- Citations by year
- 2026: 1 · 2025: 1 · 2023: 2 · 2021: 1 · 2020: 2
- FWCI
- 0.36
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Physical Chemistry Chemical Physics (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Max Planck Digital Library (submittedVersion)
- JuSER (Forschungszentrum Jülich) (submittedVersion, cc-by)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- Funders
- Merck KGaA
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Chemical Reactions and Mechanisms
- Keywords
- photooxidation, hydroxyl radicals, reaction mechanism, rate constants, NOx, CF2O, collisional quenching, association complexes, atmospheric degradation, organofluorine compounds
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