Spontaneous mirror-symmetry breaking coupled to top-bottom chirality transfer: from porphyrin self-assembly to scalemic Diels–Alder adducts
Abstract
This report shows how the net supramolecular chirality that emerged by spontaneous mirror-symmetry breaking (SMSB) at the mesoscale level can be transferred towards asymmetric solution chemistry.
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Asymmetric reactions with catalytic single-handed supramolecular assemblies from SMSB yield enantio-enriched products whose configuration is left to chance.
“Asymmetric reactions performed with catalytic single-handed supramolecular assemblies obtained through a SMSB process were found to yield enantio-enriched products whose configuration is left to chance.157,354”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [354]
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References 24 · Cited by 27
- Authors
- Arlegui, A., Soler, B., Galindo, A., Arteaga, O., Canillas, A., Ribó, J. M., El-Hachemi, Z., Crusats, J., & Moyano, A.
- Affiliations
- Universitat de Barcelona (ES)
- Institut de Ciències del Cosmos (ES)
- Department of Inorganic and Organic Chemistry
- Corresponding author
- Crusats, Joaquim
- Moyano, Albert
- ORCID
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 55
- Issue
- 81
- Pages
- 12219-12222
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2977178787
- Cited by
- 27
- References
- 24
- Citations by year
- 2026: 1 · 2025: 4 · 2024: 5 · 2023: 5 · 2022: 5 · 2021: 4 · 2020: 3
- FWCI
- 1.08
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Ministry of Science, Innovation and Universities
- Agencia Estatal de Investigación (CTQ2017-87864-C2-1-P)
- European Regional Development Fund
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Properties of Aromatic Compounds
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Keywords
- supramolecular chirality, porphyrin self-assembly, J-aggregates
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