Does aromaticity account for an enhanced thermodynamic stability? The case of monosubstituted azaborines and the stereoelectronic chameleonism of the NH 2 group
Open accessAbstract
The relationship between aromaticity and thermodynamic stability and the stereoelectronic chameleonism of the amino group are analysed and discussed in the case of monosubstituted azaborines.
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HOMA, PDI, and FLU are consistent with ECRE values for azaborines.
“HOMA, PDI, and FLU are consistent with ECRE values [62].”
From Aromaticity and Antiaromaticity: How to Define Them (2025) · cites this paper as [62]
Cites
Which NICS Aromaticity Index for Planar π Rings Is Best?
Fallah-Bagher-Shaidaei, H., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2006) · Organic Letters · doi:10.1021/ol0529546 · Cited by 1,257 · see citing works
Poater, J., Fradera, X., Duran, M., & Solà, M. (2003) · Chemistry – A European Journal · doi:10.1002/chem.200390041 · Cited by 449 · see citing works
Bohmann, J. A., Weinhold, F., & Farrar, T. C. (1997) · The Journal of Chemical Physics · doi:10.1063/1.474464 · Cited by 306 · see citing works
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Aromaticity and Antiaromaticity: How to Define Them
Baranac-Stojanović, M. (2025) · Chemistry · doi:10.3390/chemistry7040127 · Cited by 14 · see citing works
Self-citation
- Authors
- Baranac-Stojanović, M., & Stojanović, M.
- Affiliations
- University of Belgrade – Faculty of Chemistry
- University of Belgrade (RS)
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 21
- Issue
- 18
- Pages
- 9465-9476
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2939985052
- Cited by
- 12
- References
- 3
- Citations by year
- 2026: 3 · 2025: 3 · 2024: 1 · 2023: 2 · 2021: 1 · 2020: 1 · 2019: 1
- FWCI
- 0.29
- Type
- journal article
- Language
- en
- Open access
- green
- cer.ihtm.bg.ac.rs
- Licence
- cc-by-nc-nd
- rsc.li/journals-terms-of-use (am, 470 d)
- Locations
- Physical Chemistry Chemical Physics (publishedVersion)
- PubMed (publishedVersion)
- CER (University of Belgrade, Institute of Chemistry, Technology and Metallurgy) (submittedVersion)
- CER (University of Belgrade, Institute of Chemistry, Technology and Metallurgy) (submittedVersion, cc-by-nc-nd)
- Cherry (Univesrity of Belgrade, Faculty of Chemistry) (submittedVersion)
- Cherry (Univesrity of Belgrade, Faculty of Chemistry) (submittedVersion, cc-by-nc-nd)
- Funders
- Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja (172020)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Properties of Aromatic Compounds
- Physical Sciences › Chemistry › Organic Chemistry › Organoboron and organosilicon chemistry
- Physical Sciences › Chemistry › Inorganic Chemistry › Synthesis and characterization of novel inorganic/organometallic compounds
- Keywords
- aromaticity, thermodynamic stability, azaborines, substituent effects, amino groups, π-electron acceptors, conformational change, ring isomers
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